Hexylene-bridged periodic mesoporous polysilsesquioxanes (HBPMS) are a promising new class of adsorbent for the removal of organic contaminants from aqueous solutions. These hybrid organic-inorganic materials have a larger BET surface area of 897 m2·g-1 accessible through a cubic, isotropic network of 3.82-nm diameter pores. The hexylene bridging group provides enhanced adsorption of organic mo...

Characterization of mesoporous adsorbents is traditionally performed in terms of the pore size distribution with bulk methods like physisorption and mercury intrusion. But their application relies on assumptions regarding the basic pore geometry. Although novel tools have enabled the quantitative interpretation of physisorption data for adsorbents having a well-defined pore structure the analys...

A multi-functional polystyrene based adsorbent (NKU-9) with a unique mesoporous and a high surface area was prepared by suspension polymerization for removal of therapeutic toxins in blood purification. The adsorbent produced had an almost equal amount of mesopore distribution in the range from 2 to 50 nm. The adsorption of serum toxins with different molecular weights were examined by in vitro...

This reaserch aims at functionalizing magnetic mesoporous silica with methacrylic acid-3-aminopropyltriethoxysilane (Fe3O4@MCM-41@MAA-APTES) applied for removal of methylene blue from aqueous solution. Several variables (such as pH, dye concentration, adsorbent amount and contact time) have been investigated. Under optimum conditions, maximum capacity of 87.71 mg g-1 of MB was obtained for the ...

Two gold-selective adsorbents were prepared from MCM-41 by grafting amino and thiol groups. The mesoporous silica adsorbents possess higher adsorption capacity for gold compared to activated carbons. The OMSNH2 adsorbent was able to selectively remove and adsorb gold from solutions containing copper. Pure gold was recovered by a simple acid wash and the regenerated adsorbents could be reused. T...

Polycyclic aromatics hydrocarbons are chemical species with two to six fused benzene rings and are well-known toxic hazardous pollutants and highly potent carcinogens that can cause tumors in some organisms.1 In recent years, naphthalene contamination in water systems has drawn increasing attention. Naphthalene originates from natural and anthropogenic sources. Anthropogenic sources include eng...

Development of quantitative theory of adsorption-induced deformation is important, e.g., for enhanced coalbed methane recovery by CO2 injection. It is also promising for the interpretation of experimental measurements of elastic properties of porous solids. We study deformation of mesoporous silica by n-pentane adsorption. The shape of experimental strain isotherms for this system differs from ...

Mesoporous silica SBA-15 was synthesized using P123 as surfactant and functionalized with (3-chloropropyl) triethoxysilane. For the first time, the composite of THPP-SBA-15 was prepared using incorporation of tetrakis(4-hydroxyphenyl)porphyrin in functionalized SBA-15. The materials were characterized by BET, SEM, XRD, FT-IR, DRS, and UV–Vis spectroscopy techniques. The synthesized composite wa...

In this study, amine functionalized Kit-6 silica mesoporous magnetite nanocomposite (NH2-MMNC) was synthesized by chemical methods and used as an efficient and recoverable adsorbent for removal of Ponceau 4R, as a toxic dye, from aqueous solutions. The synthesized nanocomposites were characterized by XRD, FT-IR, BET and SEM instruments. The effect of various experimental parameters on the dye r...

Adsorption of typical pharmaceuticals and personal care products (PPCPs) (such as naproxen, ibuprofen and oxybenzone) from aqueous solutions was studied by using the highly porous metal-organic framework (MOF) MIL-101 with and without functionalization. Adsorption results showed that MIL-101s with H-donor functional groups such as -OH and -NH2 were very effective for naproxen adsorption, despit...