Derivatives were prepared from N-linked glycans by reductive amination from 2-aminobenzamide, 2-aminopyridine, 3-aminoquinoline, 2-aminoacridone, 4-amino-N-(2-diethylaminoethyl)benzamide, and the methyl, ethyl, and butyl esters of 4-aminobenzoic acid. Their electrospray and collision-induced dissociation (CID) fragmentation spectra were examined with a Q-TOF mass spectrometer. The strongest sig...

background: the removal of toxic metals from sewage and wastewaters is one of the most important concerns in the twenty first century. the removal of poisonous cr(vi) from aqueous solution by different low-cost available nanoporous adsorbents was investigated in the present study.  methods: fumed silica, bentonite (bn), hydrotalcite (ht), mcm-41, na-y, mordenite (mor) and sapo-34 were used at d...

The glycolipids such as sulfoquinovosyl diacylglycerol (SQDG), isolated from wild-type cyanobacterium Synechocystis sp. PCC 6803, and monogalactosyl diacylglycerol (MGDG) and digalactosyl diacylglycerol (DGDG), obtained from whole wheat Ñour, have been investigated by using fast atom bombardment tandem mass spectrometry (FAB-MS/MS). Collision-induced dissociation (CID) of sodium-adduct molecula...

The mechanism by which K(+) channels select for K(+) over Na(+) ions has been debated for the better part of a century. The prevailing view is that K(+) channels contain highly conserved sites that selectively bind K(+) over Na(+) ions through optimal coordination. We demonstrate that a series of alternating sites within the KcsA channel selectivity filter exists, which are thermodynamically se...

measurements of pb, cu, zn, as, ni, hg, and fe heavy metals and major elements and components such as ca, hco3, so4, na, k, mg and cl in soluble rain fractions were performed on rainwater collected at arak plain during the rainy seasons of 2012. concentrations of the heavy metals in the soluble fractions decreased for fe, pb, zn, ni, cu, as and hg, respectively and the major elements and compon...

Cyclic nucleotide-gated channels are key components in the transduction of visual and olfactory signals where their role is to respond to changes in the intracellular concentration of cyclic nucleotides. Although these channels poorly select between physiologically relevant monovalent cations, the gating by cyclic nucleotide is different in the presence of Na(+) or K(+) ions. This property was ...

Condensation of monovalent counterions around DNA influences polymer properties of the DNA chain. For example, the Na(+) ions show markedly stronger propensity to induce multiple DNA chains to assemble into compact structures compared with the K(+) ions. To investigate the similarities and differences in the sodium and potassium ion condensation around DNA, we carried out a number of extensive ...

Matricaria chamomilla is a medicinal plant that is widely cultivated in salt affected soils. This investigation was undertaken to study the effect of NaCl concentration on germination, and the physiological, biochemical and growth characteristics of chamomile. Seed germination and growth were studied at five NaCl concentration levels (0, 40, 80, 120 and 190 mM NaCl concentration). Increasing th...

Bullfrog sympathetic ganglion cells were capable of producing action potentials (Ca spikes) in an isotonic (84 mM) CaCl2 solution. The peak level of Ca spikes showed an approximately 30 mv increase with a 10-fold increase in the Ca concentration. Na as well as Ca ions were capable of acting as charge carriers during the production of action potentials in a solution containing relatively high Ca...

We developed a method to elucidate the complete structure of triacylglycerols by means of high-energy collisional activation tandem mass spectrometry (MS/MS). Both ESI- and FAB-produced [M + NH4]+ and [M + met.]+ ions (where met. = Li, Na, and Cs) of triacylglycerols undergo charge-remote and charge-driven fragmentations. We emphasize the study of fragment ions from ESI-produced [M + NH4]+ and ...