Recent years have seen increasing interest in the potential for using caesium-137 as a tracer in soil erosion investigations and caesium-137 measurements are now accepted as an effective and valuable means of producing retrospective information on medium-term rates and patterns of soil redistribution. There are, however, two important limitations to the general application of the approach. Thes...

The synthesis of two new polyaminocarboxylate macrocycles incorporating one or two intracyclic phenol units (H4L1 and H8L2, respectively) is described. The 12-membered H4L1 macrocycle leads to soluble and stable mononuclear LnIII complexes of [(L1)Ln(H2O)2]- composition (Ln = Eu, Tb and Gd) in aqueous solutions. In Tris buffer (pH 7.4), the [(L1)Tb(H2O)2]- complex displays a suitable efficiency...

The search for new stationary phases has been one of the predominant concerns in high performance liquid chromatography (HPLC) in order to achieve better resolutions, longer column lives, and reduce the time of analysis. A chromatographic packing for separation of underivatized amino acids (AAs) were prepared by dynamically coating 2-amino tetraphenyl prophyrin (atpp) on a C-18 reversed-pha...

The reaction of cinchonidine (cinchonine)-derived ammonium salts with nitroolefins in the presence of Cs2CO3 to afford optically active isoxazoline N-oxides with excellent ee and high de values has been developed.

This paper explores the usage of microfocus X-ray computed tomography (CT) for visualization and quantification of diffusion phenomena in cracked concrete. Mortar specimens of varying shapes (prismatic and cylindrical), crack types (artificial and splitting tensile), and binder compositions (OPC and fly ash) were prepared. Cesium carbonate (Cs2CO3) was used as a tracer in the diffusion test bec...

X-Ray scattering measurements of 2.78 and 5.56 molal aqueous solutions of caesium iodide and 2.78 and 6.05 molal lithium iodide were carried out at 293 and 343 K Differences in the radial distribution functions (DRDFs) have been obtained between the caesium iodide and lithium iodide solutions of similar composition, the latter being taken as a reference for the data analysis of the former. The ...

Single crystals of caesium tantalate(V), Cs(10)Ta(29.27)O(78), were obtained as a serendipitous product in a welded tantalum ampoule by a blank reaction of CsBr and bis-muth subnitrate [Bi(5)O(OH)(9)(NO(3))(4)] with the container material. The crystal structure of the title compound is made up of a three-dimensional framework constituted by two types of layers, viz. (Ta(6)O(15))(n) and (Ta(3)O(...

the search for new stationary phases has been one of the predominant concerns in high performance liquid chromatography (hplc) in order to achieve better resolutions, longer column lives, and reduce the time of analysis. a chromatographic packing for separation of underivatized amino acids (aas) were prepared by dynamically coating 2-amino tetraphenyl prophyrin (atpp) on a c-18 reversed-phase p...

Since several days, radioactive pollution was observed in the marine environment, at varying distances from the Fukushima-Daiichi power station. The main radionuclides regularly found in the sea water are (T = radioactive half-life): iodine 131 (T = 8 days), caesium 137 (T = 30 years), caesium 134 (T = 2.1 years), caesium 136 (T = 13.1 days), tellurium 132 / iodine 132 (T = 78 hours). Others ha...