Kinetic isotope effects related to the breaking of chemical bonds drive sulfur isotope fractionation during dissimilatory sulfate reduction (DSR), whereas oxygen isotope fractionation duringDSR is dominated by exchange between intercellular sulfur intermediates and water. We use a simplified biochemical model for DSR to explore how a kinetic oxygen isotope effect may be expressed. We then explo...

Abstract Effective recycling of zinc-containing industrial wastes, most importantly electric arc furnace dust, is tremendous importance for the circular economy steel and zinc industry. Herein, we propose a comprehensive kinetic model combined carbothermic metallothermic reduction oxide in metal bath process. Pyro-metallurgical, large-scale lab experiments carbon-saturated iron melt as agent mo...

The present paper investigated the thermodynamics and kinetics of carbothermal reduction fayalite by non-isothermal method combining with thermogravimetric analyzer applying Flynn-Wall-Ozawa (FWO) M?lek models. According to thermodynamic analysis, starting temperature direct reaction was 806.79? in standard state. indirect could not take place While volume percentage CO higher than 86 vol.% non...

Pairing occurs in conventional superconductors through a reduction of the electronic potential energy accompanied by an increase in kinetic energy. In the underdoped cuprates, optical experiments show that pairing is driven by a reduction of the electronic kinetic energy. Using the dynamical cluster approximation we study superconductivity in the two-dimensional Hubbard model. We find that pair...