Isotopic composition of reactants affects the rates of chemical and biochemical reactions. As a rule, enrichment of heavy stable isotopes leads to progressively slower reactions. But the recent isotopic resonance hypothesis suggests that the dependence of the reaction rate upon the enrichment degree is not monotonous. Instead, at some "resonance" isotopic compositions, the kinetics increases, w...

Trace metal clean plankton tows, river samples, aerosol leachates, and porewater samples from the Amazon River system were measured for their iron isotopic composition. The overall isotopic range observed was 1.5‰ with Fe isotopic variability observed between different types of tributaries. Dissolved Fe and suspended load Fe from two main channel sites were isotopically similar (≈ −0.1 to −0.3‰...

Nitrous oxide is an important greenhouse gas and ozone-depleting-substance. Its sources are diffuse and poorly characterized, complicating efforts to understand anthropogenic impacts and develop mitigation policies. Online, spectroscopic analysis of N2O isotopic composition can provide continuous measurements at high time resolution, giving new insight into N2O sources, sinks, and chemistry. We...

The Lalezar granitoids crop out within volcanic successions of the Urumieh-Dokhtar Magmatic Assemblage (UDMA). These granitoids have a range from gabbro-diorites to granites in composition. The mineral compositions of the most felsic rocks are characterized by the abundances of Na-plagioclase, quartz, alkali feldspar, biotite and hornblende. In the gabbro-diorite rocks, plagioclase (Ca-rich), h...

We have measured the concentration and isotopic composition of lead in blood over a 15-month period for a subject who undertook recreational shooting in outdoor and indoor firing ranges on an irregular basis. We have also measured the isotopic composition in cast lead, Cu-jacketed and Teflon-coated bullets, propellant and primer from which he assembled the cartridges. Blood lead concentration i...

In order to identify the function of uncultured microorganisms in their environment, the SIMSISH method, combining in situ hybridization (ISH) and nanoscale secondary ion mass spectrometry (nanoSIMS) imaging, has been proposed to determine the quantitative uptake of specific labelled substrates by uncultured microbes at the single cell level. This technique requires the hybridization of rRNA ta...

[1] The isotopic anomaly of oxygen in atmospheric CO2 is caused by exchange reactions with isotopically anomalous O(D) in the middle atmosphere. In the stratosphere, the major source of O(D) is O3 photolysis; O3 is known to possess mass-independent isotopic composition, with dO3 dO3 100% relative to atmospheric O2. Higher in the mesosphere, Lyman a-driven photodissociation of O2 provides a more...

Deep-sea pore fluids are potential archives of ancient seawater chemistry. However, the primary signal recorded in pore fluids is often overprinted by diagenetic processes. Recent studies have suggested that depth profiles of Mg concentration in deep-sea carbonate pore fluids are best explained by a rapid rise in seawater Mg over the last 10–20 Myr. To explore this possibility we measured the M...

Seabird excrements (guano) have been preserved in the arid climate of Northern Chile since at least the Pliocene. The deposits of marine organic material in coastal areas potentially open a window into the present and past composition of the coastal ocean and its food web. We use the stable isotope composition of nitrogen and carbon as well as element contents to compare the principal prey of t...