This paper presents the result of applying POD (Proper Orthogonal Decomposition) and IHMPC (Infinite Horizon Model Predictive Control) to the control of a non-isothermal tubular reactor. This paper is based on a previous work of O.M. Agudelo, J.J. Espinosa, B. De Moor Control of a Tubular Chemical Reactor by means of POD and Predictive Control Techniques, in Proceedings of the European Control ...

An isothermal reactor in which reaction solutions can be controlled at constant temperature under constant microwave irradiation was developed. This is useful for investigating microwave effects on chemical reactions that are not observed under conventional heating conditions. We devised a structure in which a heat-transfer medium with a low dielectric loss factor, which hardly absorbs any micr...

Infinite time optimal controllers have been designed for a dispersion type tubular reactor model by using the framework of adaptive critic optimal control design. For the reactor control problem, which is governed by two coupled nonlinear partial differential equations, an optimal controller synthesis is presented through two sets of neural networks. One set of neural networks captures the rela...

Hydrocracking has great importance in present day refining due to strict environmental and norms of quality of fuel. In recent years the demand for middle distillate and gasoline has increased tremendously while that of heavy gas has decreased. In the present work we have modeled and then applied five lump scheme to hydrocracker reactor. The first order kinetics was assumed for the conversion i...

This paper proposes a new MINLP model for heat exchanger network synthesis that includes streams with phase change. The model considers every possible combination of process streams that may arise within a chemical process: streams with sensible heat, streams with latent heat, and streams with both latent and sensible heat. As part of the optimization strategy, the superstructure is modeled wit...

We study the existence and uniqueness of traveling wave solutions for a class of twocomponent reaction diffusion systems with one species being immobile. Such a system has a variety of applications in epidemiology, bio-reactor model, and isothermal autocatalytic chemical reaction systems. Our result not only generalizes earlier results of Ai and Huang (Proceedings of the Royal Society of Edinbu...

A coupled system of two isothermal in vitro DNA/RNA amplification reactions using different primers is modeled kinetically with realistic rate parameters and shown to exhibit oscillatory behavior in a flow reactor. One of the two isothermal amplification reactions acts as a predator of the other, the prey. The mechanism of the oscillatory behavior is analyzed in terms of a hierarchy of kinetic ...

The paper deals with nonlinear control under input constraints of a non isothermal Continuous Stirred Tank Reactor (CSTR) using thermodynamic concepts. More precisely, the paper presents an extension of the previous work (Hoang et al. (2012)) where the jacket temperature is used as the only control input. Constrained input control strategy is based on the observation that the chemical reactor o...

This paper shows that any thermodynamic potential fulfilling some thermodynamic stability criterion (e.g. the chemical affinity or the ectropy) can be used as a potential function for the dissipative (pseudo) Port Hamiltonian formulation of the non isothermal Continuous Stirred Tank Reactor (CSTR) model. Besides Brayton-Moser formulation is used to obtain some dissipative Port Hamiltonian repre...

The paper presents a simplified model of chemical looping combustion in a fixed bed reactor under isothermal condition. Both reduction and regeneration phases of the oxygen carrier are modeled in the single reactor model under the hypothesis of discontinuous feed and simplified reaction kinetics. This model is meant to be the simplest possible formulation for a description that incorporates all...