ABSTRACT In electrostatic repulsive interaction chromatography, using a charged surface hybrid sorbent carrying positive charges can improve the peak shape of peptides in reversed-phase liquid chromatography (RP-LC), especially in overloaded conditions, compared with standard C18 sorbents. However, the positive surface charges can interact with anionic additives commonly used in peptide separat...

The purpose of this study is to investigate the capacity of natural Turkish zeolite for NH4-N removal from landfill leachate. The effects of modification and initial concentration on the removal of NH4-N from leachate were also investigated. The kinetics of adsorption of NH4-N has been discussed using three kinetic models, i.e., the pseudo-second order model, the Elovich equation, the intrapart...

adsorption of p-nitrophenol by three different activated carbons (f100, s.e.i. and b.d.h.) was carried out at 301 k and at controlled ph conditions. two different adsorption models (langmuir model and freundlich model) were studied and compared. the adsorption capacity of the carbons depends on the point of zero charge (pzc) and surface area of the carbons. adsorption of the solute at higher ph...

Chemically modified kenaf core fibres were prepared via esterification in the presence of citric acid (CA). The adsorption kinetics and isotherm studies were carried out under different conditions to examine the adsorption efficiency of CA-treated kenaf core fibres towards methylene blue (MB). The adsorption capacity of the kenaf core fibres increased significantly after the citric acid treatme...

Few studies have combined molecular- and macroscopic-scale investigations with surface complexation model (SCM) development to predict trace metal speciation and partitioning in aqueous systems over a broad range of conditions. In this work, an extensive collection of new macroscopic and spectroscopic data was used to assess the ability of the modified triple-layer model (TLM) to predict single...

in this study adsorption of 1-chloro-4-nitrobenzene (cnb) from aqueous solutions onto multi-walled carbon nanotubes (mwcnts) was surveyed. the effect of some key parameters such as ph (2-10), carbon nanotubes dosage (0.02-0.1 mg/250ml), cnb concentration (2- 16 mg/l), and temperature (20,30,40,50°c) were investigated. the results showed that, the variation of initial ph and cnb concentration ex...

We use the Percus-Yevick approximation to study indirect correlation functions in the sticky hard-sphere model introduced by Baxter. The model has a critical point below which there is a liquid gas transition. We illustrate the changes in the structure of the correlation function as the density increases on the critical isotherm and on supercritical and subcritical isotherms. We also examine th...