Nitrate Ion-Separation The underlying prerequisite for materials design to achieve on-target separation of low nucleophilic nitrate ions has been unclear. By fabricating cation-ordered layered double hydroxides (LDHs) via topochemical reaction, in article number 2201484, Tomohito Sudare, Katsuya Teshima, and colleagues demonstrate that the hexagonal arrangement effectively facilitates a stable ...

A new category of hybrid organic-inorganic zirconium phosphonate, Zr[(O3PCH2)2NC6H4CO2H].2H2O was synthesized and the applicability of the prepared sorbent as an ion-exchanger for removal of Ni2+, Cu2+ and Zn2+ from aqueous solutions was evaluated. The characterization of the synthe...

The ability to separate isotopes by high-resolution ion mobility spectrometry techniques is considered as a direct means for determining mass at ambient pressures. Calculations of peak shapes from the transport equation show that it should be possible to separate isotopes for low-mass ions (<200) by utilizing heavy collision gases and high-resolution ion mobility analyzers. The mass accuracy as...

On the basis of the perturbation expansion for electron gas energy in the third order to the electron-ion potential the pair and irreducible three-ion interaction potentials in metallic hydrogen are calculated. The irreducible potential of three-ion interaction has attractive nature at short interionic separation and oscillates at large ones. The anisotropic character of the three-ion interacti...

The hybrid molten/solid In2O3 - 30-48 wt.% Bi2O3 oxide materials were studied with respect to their transport properties. The conductivities, oxygen ion transport numbers and oxygen permeation fluxes have been measured by using the four-probe DC, volumetric measurements of the faradaic efficiency and gas flow techniques, respectively. We show that the...

The engineering considerations common to large scale chromatographic purification of proteins are reviewed. A discussion of the industrial chromatography fundamentals is followed by aspects which affect the scale of separation. The separation column geometry, the effect of the main operational parameters on separation performance, and the physical characteristics of column packing are treated. ...