The adsorption of CO2 and CH4 in a mixed-ligand metal-organic framework (MOF) Zn 2(NDC) 2(DPNI) [NDC = 2,6-naphthalenedicarboxylate, DPNI = N, N'-di-(4-pyridyl)-1,4,5,8-naphthalene tetracarboxydiimide] was investigated using volumetric adsorption measurements and grand canonical Monte Carlo (GCMC) simulations. The MOF was synthesized by two routes: first at 80 degrees C for two days with conven...

An experimental study has been made of the adsorption of gelatin from solution at 37 degrees C. by collodion membranes. In the case of membranes of high permeability, very high concentrations of gelatin were required to produce maximum adsorption, and the maximum amounts adsorbed were independent of the pH values of the solutions over the range 3.8 to 4.8. With membranes of low permeability, ma...

An old question of T. Jech and K. Prikry asks if an existence of a precipitous ideal implies necessary existence of a normal precipitous ideal. The aim of the paper is to prove some results in the positive direction. Thus, it is shown that under some mild assumptions, an existence of a precipitous ideal over א1 implies an existence of a normal precipitous ideal over א1 once a Cohen subset is ad...

A published model for estimating service lives of organic vapor (OV) air-purifying respirator cartridges has been extended to include multiple organic vapors at all humidities. Equilibria among the OVs are calculated using Ideal Adsorbed Solution Theory, whereas the effects of adsorbed water are considered as due to micropore volume exclusion. Solubilities of OVs in water must also be taken int...

the ideal theory is plato’s most important philosophical view involving his allegory of the cave. he tried much to explain this theory and present arguments in order to prove it. however, his views on the proof arguments and the concrete materials with ideals suffer from shortcomings. the present paper argues that the critiques of aristotle, avicenna, and allamah tabatabaee against this theory ...

Configurational-bias Monte Carlo (CBMC) simulations are used to establish the potential of CuBTC for separation of water/benzene, methanol/benzene, ethanol/benzene, and acetone/benzene mixtures. For operations under pore saturation conditions, the separations are in favor of molecules that partner benzene; this is due to molecular packing effects that disfavor benzene. CBMC simulations for adso...

The equilibration of polymer conformations tends to be sluggish in polymer layers adsorbed onto highly attractive substrates, so the structure of these layers must be understood in terms of the layer growth process rather than equilibrium theory. Initially adsorbed chains adopt a highly flattened configuration while the chains which arrive later must adapt their configurations to the increasing...