A decoupled control law is proposed to control the concentration of monomer in the polymer particles in emulsion homopolymerization, copolymerization and terpolymerization processes and simultaneously to insure the production of a homogeneous polymer composition. Nonlinear geometric controllers are used to calculate the monomer flow rates that accomplish this purpose. The controllers are based ...

Novel non-ionic hydrogels were synthesized by radical homopolymerization of N-vinyl-2-pyrrolidone (VP) or by radical copolymerization of VP with methylacrylate (MA). A macroinimer (MIM) was used as a crosslinker and initiator, as well. The percentage of mass swelling ratios (S(M)), the molecular weight between crosslinks (M(c)) and Young's modulus of the hydrogels were investigated. The hydroge...

A series of anilido–imine chromium complexes have been used as precursors to catalyze homoand copolymerization of ethylene and norbornene. The chromium complexes activated with methylalumoxane (MAO) exhibit good activities for homopolymerization of ethylene (E) to produce linear polyethylene and moderate activities for norbornene (N) polymerization to afford vinyl-type polynorbornene. Ethylene–...

A series of novel Ni(II) and Pd(II) complexes bearing chiral bis(β-ketoamino) ligand were synthesized characterized. The exhibited high activities for norbornene homopolymerization with only B(C 6 F 5 ) 3 as cocatalyst, complex even up to 1.38 ×10 g polymer /mol Ni ·h. All the had good thermal stability. Most importantly, also displayed 10 metal ·h toward copolymerization 5-norbornene-2-yl acet...

Transition metal-catalyzed copolymerization of CO and ethylene has a strong inherent propensity to produce the strictly alternating copolymer. In this work, nickel catalysts capable both homopolymerization are developed explore possibility non-alternating under assumption that comonomer incorporation in polymer chain can be adjusted by concentrations comonomers. Both polyketones with slightly m...