The oxidation of cumene and following cleavage hydroperoxide (CHP) with sulfuric acid (Hock rearrangement) is still, by far, the dominant synthetic route to produce phenol. In 2020, global phenol market reached a value 23.3 billion US$ projected compound annual growth rate 3.4% for 2020–2025. From ecological economical viewpoints, key step this process CHP. One sought-after way likewise reduce ...

Solid acid catalysts are becoming of great importance within the chemical industry and their acidity is of great interest, as this determines their application, plus many of their catalytic properties can also be directly related with their acidity. There has been a drive towards heterogeneous solid acid catalysts because of the environmental concerns with safe handling and disposal of mineral ...

We developed a facile strategy for preparation of heteropoly metalate/graphene oxide nanocomposite as a new ion exchanger for cadmium ion removal from aqueous solution. The synthesized nanocomposite was characterized by X-ray powder diffraction (XRD), UV-Vis spectroscopy, FT-IR spectroscopy and Raman spectroscopy. Our findings indicated that the combination of heteropoly metalate nanoparticles ...

The production of ethylen tially attractive, since the carbon source than petrol bonylation using methyl f used as the catalyst. Met were formed along with of formaldehyde source, r paraformaldehyde, 1,3,5-t The highest yields of met as the source of formalde and limited the rate of ca the highest yields of meth produce these products at methanesulfonic acid is a the reactive intermediates

Acidic heteropoly salt Cs(2.5)H(0.5)PW(12)O(40) doped with Pt nanoparticles is a highly active and selective catalyst for one-step hydrogenation of methyl isobutyl and diisobutyl ketones to the corresponding alkanes in the gas phase at 100 °C with 97-99% yield via metal-acid bifunctional catalysis.

Fossil additives are a primary energy source and their contribution is around 80% in the world. Therefore, bioadditives that reduce impact each very important. This article discusses chemical transformation of glycerol to carbonate, ethers, esters, ketals, acetals, compounds with high technological applications, especially fuel sector as bioadditives. Mainly, heterogeneous catalysts important p...