The oligomerization of biomass-derived light olefins offers a promising potential for the synthesis sustainable jet-fuels, which mostly comprise C10-C18 hydrocarbons. However, selectivity control reaction remains challenge. In this contribution, pentene and hexene mixtures was studied over acidic mesoporous Al–SBA–15 catalyst in continuous operation, impact different process parameters on conve...

abstract: in this study an appropriate computational approach was presented for estimating the boiling temperatures of 41 different types of olefins and their derivatives. based on the guidelines of this approach, several structural indices related to the organic components were applied using graph theory. meanwhile, in addition to evaluating the relation between the boiling temperatures of ole...

Abstract: In this study an appropriate computational approach was presented for estimating the boiling temperatures of 41 different types of olefins and their derivatives. Based on the guidelines of this approach, several structural indices related to the organic components were applied using graph theory. Meanwhile, in addition to evaluating the relation between the boiling temperatures of ole...

The epoxidation reaction using heterogeneous solid catalysts with H2O2 as oxidants are environmentally friendly routes to produce extensively useful epoxides which are traditionally obtained from capital-intensive or environmentally polluted processes. In this paper, various types of solid catalysts for the epoxidation of olefins with H2O2 as oxidants are reviewed. The efficient catalysts repor...

Human betaB1-crystallin is a major eye-lens protein that undergoes in vivo truncation at the N-terminus with aging. By studying native betaB1 and truncated betaB1DeltaN41, which mimics an age-related in vivo truncation, we have determined quantitatively the effect of truncation on the oligomerization and phase transition properties of betaB1 aqueous solutions. The oligomerization studies show t...

As a significant reaction in heterogeneous catalysis, methanol-to-hydrocarbon (MTH) conversion supplies sustainable way for the production of important platform chemicals, e.g., olefins, gasoline and aromatics. Although many commercial MTO plants have already been operated China recently, catalytic efficiency, i.e., olefins selectivity catalyst lifetime still need to be improved. Consequently, ...

The oxidative cracking of n-decane was investigated at millisecond contact times over platinum alumina washcoated monoliths a fuel-air equivalent ratio (Φ) 5. High valuable linear α-olefins were so produced through an autothermal way concomitantly with oxygenated compounds, CO, CO2, H2 and H2O. A fine identification reaction products coupled the study thermal phenomena occurring both active dea...