The study of protein conformation by solution-phase hydrogen/deuterium exchange (HDX) coupled to MS is well documented. This involves monitoring the exchange of backbone amide protons with deuterium and provides details concerning the protein's tertiary structure. However, undesired back-exchange during post-HDX analyses can be difficult to control. Here, gas-phase HDX-MS, during which labile h...

2014 We have measured the mobility of positive ions in several gas mixtures frequently used in proportional and drift chambers, namely Ar-(OCH3)2CH2, Ar-(OCH3)2CH2-IsoC4H10, Ar-CH4, and Ar-CO2. In all gas mixtures considered, Blanc’s law of positive ion mobility has been verified, except for a very small methylal concentration in argon-isobutane-methylal. The law permits the calculation of ion ...

Objective: To find the impact of impaired upper limb motor function on trunk control and mobility in chronic post-stroke survivors so that the upper limb function should be enhanced as a core component of rehabilitation. Methods: This analytical cross-sectional study was conducted from March 2021 to August 2021 at Rehabilitation Center for the Physically Disabled, Peshawar, Pakistan. A total o...

The present sought to draw a comparison between Model Predictive Control performance and two other controllers named Simple PI and Selective PI in controlling large-scale natural gas transport networks. A nonlinear dynamic model of representative gas pipeline was derived from pipeline governing rules and simulated in SIMULINK® environment of MATLAB®. Control schemes were designed to provide a s...

Carbon dioxide has been used commercially to recover oil from reservoir by enhanced oil recovery technologies for over 40 years. Currently, the CO2 flood is the second most applied enhanced oil recovery (EOR) processes in the world behind steam flood. Water alternating gas (WAG) injection has been a popular method to control mobility and improve volumetric sweep efficiency for CO2 flooding. The...

Studying biological systems to determine structure has been performed by a number of analytical techniques, including electrospray ionization (ESI)/ion mobility spectrometry (IMS) with mass spectrometry (MS) detection. ESI/IMS/MS enables the determination of gas phase ionic molecular size and can be correlated to computational modeling for structural evaluation. In this study, a molecular model...

A number of peptides were studied with electrospray ionization--ion mobility spectrometry/mass spectrometry (ESI-IMS/MS). The ion mobility data were used to calculate the average collision cross sections of the different detected peptide ions in the nitrogen drift gas. By comparing the cross sections of related ions, structural information about the most probable location of the charge and the ...

The oxidation characteristics of airborne carbon nanoparticles were investigated at various temperatures and NO(2) concentrations. Airborne carbon nanoparticles were generated by spark-discharging method using nitrogen as a carrier gas. Monodisperse carbon particles classified using a differential mobility analyzer were introduced into a tube furnace with NO(2) for oxidation reaction. The size ...