Influence of synthesis temperature on morphology of SBA-16 mesoporous materials with a three-dimensional pore system, Abstract Spherical particles of mesoporous silica SBA-16 with cubic Im3m structure were synthesized at low pH using Pluronic F127 as template and TEOS as silica source. The diameter of the spherical particles can be controlled in the range of 0.5 – 8 µm by varying synthesis temp...

In this study, bimodal mesoporous silica, i.e. UVM-7, was synthesized and functionalized withsulfonic acid and characterized using XRD, nitrogen physisorption, SEM, TEM and acid/basetitration. The results displayed that bimodal mesopore structure was firmly formed and acidicfunctional groups were grafted on the surface of the UVM-7. The concentration of the acidicfunctional groups was determine...

knoevenagel condensation between barbituric acid and aldehyde was investigated in the presence of sulfonic acid functionalized nanoporous silica (sba-pr-so3h) and resulted in the formation of arylidene and bis-arylidene barbiturates. excellent yields and short reaction times are related to the high efficiency of sba-pr-so3h that the reactions take place easily in its nano-pores. sba-pr-so3h as ...

By controlling the interaction between cationic surfactant micelles and ammonium metatungstate during the formation of mesoporous silica structure, highly dispersed tungsten carbide (WC) nanoparticles of 2.0 nm in diameter on mesoporous silica nanospheres were synthesized at lower concentration of ammonium metatungstate. With additional ammonium metatungstate, a novel mesoporous silica nanobamb...

Knoevenagel condensation between barbituric acid and aldehyde was investigated in the presence of sulfonic acid functionalized nanoporous silica (SBA-Pr-SO3H) and resulted in the formation of arylidene and bis-arylidene barbiturates. Excellent yields and short reaction times are related to the high efficiency of SBA-Pr-SO3H that the reactions take place easily in its nano-pores. SBA-Pr-SO3H as ...

in this research, mesoporous silica was applied as the host of corrosion inhibitor (molybdate). the loaded mesoporous silica was dispersed in an epoxy matrix. the composite was then coated on the mild steel plate. results showed that the corrosion resistance of the scratched epoxy/mesoporous silica loaded by molybdate was better than the one without molybdate or neat epoxy. on the other hand, e...

Hollow mesoporous silica spheres have recently attracted increasing attention. However, effective synthesis of uniform hollow mesoporous spheres with controllable well-defined pore structures for fundamental research and practical applications has remained a significant challenge. In this work, a straightforward and effective "cationic surfactant assisted selective etching" synthetic strategy w...

Eu ions-doped cubic mesoporous silica thin films with a thickness of about 205 nm were prepared on silicon and glass substrates using triblock copolymer as a structure-directing agent using sol–gel spin-coating and calcination processes. X-ray diffraction and transmission electron microscopy analysis show that the mesoporous silica thin films have a highly ordered body-centered cubic mesoporous...