Fluorine interaction assisted AIEE characteristic in an expanded calixbenzophyrin is presented by single-crystal X-ray-diffraction analysis and molecular modelling approaches. Selective exposure to volatile organic compounds such as ketones and esters results in the breaking of fluorine interaction, leading to enhanced monomer emission.

Introduction Perfluorocarbon (PFC) emulsions have been widely used for cell tracking studies [1,2] and many other biological applications [3]. In contrast to conventional H contrast agents, F markers provide unambiguous signal in vivo due to the low natural abundance of fluorine in living organisms. Furthermore, fluorine markers can possess a unique spectral signal, a further advantage of F MR....

Fluoride, the ionic form of fluorine, is a natural component of the biosphere and 13th most abundant element in the crust of the earth. It is, therefore, found in a wide range of concentrations in virtually all inanimate and living things. Many trace elements perform a definite function in human metabolism and the question of the value of fluoride, always found in the body, has been raised. Muc...

the use of recycled bassanite, produced from gypsum wastes, in ground improvement projects is initiated recently in japan to eliminate the huge quantities of gypsum wastes. meanwhile the use of recycled bassanite has a positive effect on the environment and economy, it has many challenges. these challenges are related to the release of fluorine more than the standard limits results in contamina...

Silica gel loaded with saturated Al(N03)3. 10. H20 solution proved to be an efficient absorbent for the elimination of the interference of fluorine in the microdetermination of carbon and hydrogen in organofluorine compounds. The reagent is cheap, readily available and easily prepared. Three grams are sufficient for 25 determinations. Samples are burnt in a flow of oxygen using the rapid straig...

The partitioning of space with Hirshfeld surfaces enables the analysis of fingerprint molecular interactions in crystalline environments. This study uses the decomposition of the crystal contact surface between pairs of interacting chemical species to derive an enrichment ratio. This quantity enables the analysis of the propensity of chemical species to form intermolecular interactions with the...