نتایج جستجو برای: fischers synthesis
تعداد نتایج: 409267 فیلتر نتایج به سال:
A simple quantitative approach to enable chemists to compare alternative chemical syntheses on the lab bench with respect to their resource usage and their potential environmental impact is proposed; this may be useful for the systematic design of more sustainable processes. We consider as metrics the mass index S(-1) and the environmental factor E to characterize quantitatively the reaction in...
We present a language to specify syntax guided synthesis (SyGuS) problems. Syntax guidance is a prominent theme in contemporary program synthesis approaches, and SyGuS was first described in [1]. This paper describes concretely the input format of a SyGuS solver.
This paper describes our on-going work in the area of text-tospeech synthesis, specifically on concatenative techniques. Our preliminary work consisted in investigating the current trends in concatenative synthesis and the problems that could arise when we apply the existing state-of-the art solutions to the specific case of European Portuguese. Our ultimate goal is to develop a text-to-speech ...
Regions of nonmodal phonation, exhibiting deviations from uniform glottal-pulse periods and amplitudes, occur often and convey information about speakerand linguistic-dependent factors. Such waveforms pose challenges for speech modeling, analysis/synthesis, and processing. In this paper, we investigate the representation of nonmodal pulse trains as a sum of harmonically-related sinewaves with t...
هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
ماکروسیکلهای شیف باز از اهمیت زیادی در شیمی آلی و دارویی برخوردار می باشند. این ماکروسیکلها با دارابودن گروه های مناسب در مکانهای مناسب می توانند فلزاتی مثل مس، نیکل و ... را در حفره های خود به دام انداخته، کمپلکسهای پایدار تولید نمایند. در این پایان نامه ابتدا یک دی آلدئید آروماتیک از گلیسیرین تهیه می شود و در مرحله بعدی واکنش با دی آمینهای آروماتیک و یا آلیفاتیک در رقتهای بسیار زیاد منجر به ت...
This paper focuses on generation of expressive speech, specifically speech displaying vocal affect. Generating speech with vocal affect is important for diagnosis, research, and remediation for children with autism and developmental language disorders. However, because vocal affect involves many acoustic factors working together in complex ways, it is unlikely that we will be able to generate c...
abstract in this study, we synthesized a novel template polymer by using methacrylic acid (mma) as functional monomer, ethylene glycol dimethacrylate(egdma) as cross linker, 2,2-azobisisobutyronitrile (aibn) as initiator and olanzapine as targeted molecule in the presence of chloroform and acetonitrile as solvent. the products have been characterized and confirmed by (chn)elemental analysis,...
Like many current TTS systems the AT&T German text -tospeech system is based on the methods of unit selection and concatenative synthesis [1]. This paper highlights efforts to improve TTS quality by closely matching the speakers' original productions with linguistic descriptions. On the segmental level this is achieved by adjusting the speakers' individual productions to an established, general...
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