The complex formation and a liquid-liquid extraction in the cobalt(II) 4-(2thiazolylazo)resorcinol (TAR) 2,3,5-triphenyl-2H-tetrazolium chloride (TTC) water chloroform system was studied. The optimum extractionspectrophotometric conditions were found. The molar ratio of the reacting species was determined to be 1:2:1 (Co:TAR:TTC). The following equilibrium processes were quantitatively examined...

A rapid and sensitive method has been proposed for the determination of chromium and cobalt in seafood samples by flame atomic absorption spectrometry combined with a dynamic ultrasound-assisted acid extraction and an on-line minicolumn preconcentration. The use of diluted nitric acid as extractant in a continuous mode at a flow rate of 3.5 mL min(-1) and room temperature was sufficient for qua...

Spent Nickel cadmium batteries are classified as hazardous waste due to the presence of toxic cadmium in high concentration. Recycling of metal value by environmentally friendly process is the best option to obtain economical advantage and prevent environmental pollution. In the present investigation, a metal separation scheme is proposed for recovery of cadmium, nickel and cobalt from the leac...

A dispersive liquid–liquid microextraction based on solidification of floating organic drop for simultaneous extraction of trace amounts of nickel, cobalt and copper followed by their determination with electrothermal atomic absorption spectrometry was developed. 300 μL of acetone and 1-undecanol was injected into an aqueous sample containing diethyldithiocarbamate complexes of metal ions. For ...

In present paper the equilibrium of cobalt extraction with 1-(2-pyridyl)tridecan-1-one oxime from the chloride/sulphate solutions was studied. The presented results indicated that extraction depends on a number of process variables, including the pH, metal and Cl- concentration in the aqueous feed, and concentration of the oxime in the organic phase. The created cobalt-complexes with the 2-pyri...

cobalt is widely used in different industrial processes for production of various synthetic materials. for assessment of human exposure to toxic metal of co (ii), environmental and biological monitoring are essential processes, in which, preparation of samples is one of the most time-consuming and error-prone aspects prior to instrumental analysis. the aim of this study was to achieve optimum f...

The potential use of synergistic mixtures of reagents for the solvent extraction of nickel (and cobalt) from lateritic leach liquors was pointed out in the early 1980s by Grinstead, who used dinonylnaphthalene sulphonic acid in conjunction with some 2-pyridyl compounds for the recovery of these metals from slightly acidic solutions1,2. Shortly thereafter, studies at Mintek revealed marked syner...

A selective spectrophotometric method has been developed for the determination of cobalt after extraction of its 2-methoxyethyl xanthate complex into molten naphthalene. Cobalt reacts with this xanthate in the ratio of 1 : 2 (metal : ligand ratio) in a pH range of 3.5-9.2 and over an acid range of 2.5-7.0 M. It absorbs strongly at 355 nm. Beer's law is obeyed over the concentration range of 2.5...