Cobalt has great biological effects on human beings and also other living organisms, hence its determination is very important. In this regard, a novel coated graphite electrode was designed for determination of Co2+ ions by exploiting 6-chloro-11- azabenzo[a]phenothiazin-5-one as a neutral ion carrier, for the first time. The foremost function was witnessed from the membrane composition of PVC...

a multi-walled carbon nanotube modified paste electrode (mwcn-pe) was used for determination of promethazine (pmz) in drug formulations and blood plasma by cyclic voltammetry (cv) and differential pulse voltammetry (dpv) methods. results revealed that the mwcn-pe shows an electrocatalytic activity toward the anodic oxidation of pmz by a marked enhancement in the current response in buffered sol...

in order to study the cu(ii) ion selective electrode, an optimized membrane was prepared by mixing of 30 mg of pvc powdered, 5 mg of considered ionophore, 60 mg of plasticizer and 5 mg of additive. the sensor showed a near nernstian response for cu(ii) ions over a concentration range from 1.0×0-6 –1.0×0-2 m with a slope of 28.90.5 mv per concentration decade with a working ph range of 3.5-6.3. ...

a sensor, based on multi-wall carbon nanotubes modified glassy carbon electrode (mwcnt/gce), was developed for determination of fenitrothion. determining the surface area of mwcnt/gce showed that this surface is three times more active than that of a glassy carbon electrode. the experimental parameters, such as the amount of mwcnts, ph of the fenitrothion solution, preconcentration potential an...

a new cesium ion selective pvc membrane based on parent calix [4] arene was developed for potentiometric determination of cesium in environmental samples. the electrode based on p-5,11,17,23tetra(tertbutyl) 25,26,27,28-tetrahydroxy calix[4]arene(thc) as ionophor ,dibutyl phthalate (dbp)as plasticizer ,sodium tetra phenyl borate(natpb)and oleic acid as lipophilic salt and additive showed the ...

this paper describes the development, electrochemical characterization and utilization of novel modified molybdenum (vi) complex-carbon nanotube paste electrode for the electrocatalytic determination of ascorbic acid (aa). the electrochemical profile of the proposed modified electrode was analyzed by cyclic voltammetry (cv) that showed a shift of the oxidation peak potential of aa about 235 mv ...

in this paper, a nanostructured modified electrode was fabricated by incorporating of 2,2′-[1,9-nonanediylbis(nitriloethylidyne)]-bis-hydroquinone (nnh) as a newly synthesized modifier and tio2 nanoparticles to the carbon paste (mtcpe) and then was used for the electroanalysis of epinephrine (ep). the electrochemical studies were carried out by using cyclic voltammetry, chronoamperometry and di...

in this work, sol-gel method was used tosynthesize titanium dioxide nanoparticles (tio2). the tio2nanoparticles was characterized by scanning electron microscopy (sem), x-ray diffraction (xrd) and bet technique.the tio2 and coumarin derivative (7-(1,3-dithiolan-2-yl)-9, 10-dihydroxy-6h-benzofuro [3,2-c] chromen-6-on) were incorporated in a graphite composite electrode. the resulting modified el...

Polypyrrole (PPy) nanofibers have been fabricated on glassy carbon electrode (GCE) usingelectrochemical technique. Electropolymerization of pyrrole (Py) for the fabrication of PPy nanofiberswas occurred on GCE by applying a fixed potential of about 0.85 V for 120 sec in a mild basic solutioncontaining sodium carbonate and sodium perchlorate. In the mild basic media, the monomer, Py, isoxidized ...

This study investigated the oxidation of ascorbic acid (Vitamin C) using a platinum nanoparticle electrode coated with an iodine monolayer, called a modified electrode. The electrode were grown using the cyclic voltammetry technique and the electrochemical measurements were taken using the cyclic voltammetry and chronoamperometric technique. In the case of platinum nanoparticle electrode modifi...