Dipicolinic acid (DPA) and the Ca2+ complex of DPA (CaDPA) are major chemical components of bacterial spores. With fluorescence being considered for the detection and identification of spores, it is important to understand the optical properties of the major components of the spores. We report in some detail on the room-temperature fluorescence excitation and emission spectra of DPA and its cal...

Endothelial cell (EC) migration plays an important role in wound repair of blood vessels. We have previously reported that eicosapentaenoic acid (EPA; 20:5, n-3) pretreatment stimulates migration of ECs but not smooth muscle cells. In the present study, we used the modified Boyden chamber technique to investigate whether the stimulative effect of EPA pretreatment on EC migration is caused by EP...

AIM (18)F-DPA-714 is a PET tracer that recognizes macrophage translocator protein (TSPO), and (18)F-Alfatide II ((18)F-AlF-NOTA-E[PEG4-c(RGDfk)]2) is specific for integrin αvβ3. This study aims to apply these two tracers for longitudinal PET imaging of muscular inflammation, and evaluate the value of (18)F-DPA-714 in differentiating inflammation from tumor. METHODS RAW264.7 mouse macrophage c...

The resistance of three types of Bacillus cereus T spores to ultraviolet radiation corresponded to their dipicolinic acid (DPA) content. Photoprotection against ultraviolet light was observed in DPA-containing spores and in DPA-less spores irradiated through calcium dipicolinate.

Under a simple power leakage model based on Hamming weight, a software implementation of a data-whitening routine is shown to be vulnerable to a first-order Differential Power Analysis (DPA) attack. This routine is modified to resist the first-order DPA attack, but is subsequently shown to be vulnerable to a second-order DPA attack. A second-order DPA attack that is optimal under certain assump...

In this article we describe an improved concept for secondorder differential-power analysis (DPA) attacks on masked smart card implementations of block ciphers. Our concept allows to mount secondorder DPA attacks in a rather simple way: a second-order DPA attack consists of a pre-processing step and a DPA step. Therefore, our way of performing second-order DPA attacks allows to easily assess th...

The proteins encoded by the spoVA operon, including SpoVAD, are essential for the uptake of the 1:1 chelate of pyridine-2,6-dicarboxylic acid (DPA(2,6)) and Ca(2+) into developing spores of the bacterium Bacillus subtilis. The crystal structure of B. subtilis SpoVAD has been determined recently, and a structural homology search revealed that SpoVAD shares significant structural similarity but n...

Complexation of NpO(2)(+) with dipicolinic acid (DPA) has been investigated in 1 M NaClO(4) at 25 degrees C. Two complexes, NpO(2)(DPA)(-) and NpO(2)(DPA)(2)(3-), were identified, and the stability constants (log beta(1) and log beta(2)) were determined to be 8.68 and 12.31, respectively, by spectrophotometry. The enthalpies of the complexation (DeltaH(1) and DeltaH(2)) were measured to be -25....

Docosapentaenoic acid (22:5n-3, n-3 DPA) is a n-3 polyunsaturated fatty acid (PUFA) found in fish oil, and has been reported to have health benefits. This study investigated conversion of n-3 DPA, and examined the anti-inflammatory effects of n-3 DPA on activated macrophages. Murine macrophage-like RAW264.7 cells were incubated in culture media containing n-3 DPA for 72 h. The level of n-3 DPA ...

A kind of mesoporous hybrid luminescence material was assembled through the ion exchange method between [Ln(DPA)3](3-) and ionic liquid functionalized SBA-15. [Ln(DPA)3](3-) was successfully anchored onto positive-charge modified SBA-15 by the strong electrostatic interaction. In [Ln(DPA)3](3-), Ln(3+) ions are in 9-fold coordination through six oxygen atoms of carboxyl groups and three nitroge...