the compressibility factor of nonassociated chain molecules composed of hard convex core yukawa segments was derived with saft-vr and an extension of the barker-henderson perturbation theory for convex bodies. the temperature-dependent chain and dispersion compressibility factors were derived using the yukawa potential. the effects of temperature, packing fraction, and segment number on the com...

The accuracy and reliability of the density functional theory (DFT)-D approach to account for dispersion effects in first-principles studies of water-metal interfaces has been addressed by studying several water-metal systems. In addition to performing periodic DFT calculations for semi-infinite substrates using the popular PBE and RPBE functionals, the water dimer and water-metal atom systems ...

Quantum limit of dissipation-free photon-photon interactions at the few photon level is studied in the context of giant Kerr nonlinearities in cavity electromagnetically induced transparency (EIT). It is shown that photon-photon interaction is largest when the cavity contains a single atom. In contrast to conventional nonlinearities, increasing the number of atoms cannot increase the interactio...

The performance of double hybrid density functionals (DHDFs) has been assessed by studying the spectroscopic properties and potential energy curves of OCS-C2H4 (carbonyl sulfide-ethylene) and OCS-C4H6 (carbonyl sulfide-dimethylacetylene) van der Waals complexes. Both dispersion corrected and uncorrected DHDF theories have been applied to study the intermolecular interaction energies, stability,...

extended interaction oscillators (eio) are vacuum electronic sources of microwave, millimeter-wave and terahertz radiations. in this paper, eio is investigated by using a circuit model. the value of the coupling element in the model is evaluated from the near band-edge dispersion characteristics of the rf structure. the end external loading of the interaction structure is equivalently modeled b...

Properties of dissipative solitons generated in all-normal-dispersion fiber lasers through the gain dispersion effect are numerically studied by using a pulse-tracing technique that considers interaction between gain saturation, gain dispersion, cavity dispersion, fiber Kerr nonlinearity, and cavity boundary conditions. The numerical results qualitatively match with experimental observations an...

A simple field analysis was developed for helical slowwave structure symmetrically supported by rectangular shaped discrete dielectric support rods partially embedded in the metal segments projecting radially inward from a metal envelope for wideband traveling-wave tubes. The tape helix model was used for the prediction of the dispersion relation and the interaction impedance characteristics. T...

The dispersion interaction energy may be expressed as a sum over R(-n) terms, with n ≥ 6. Most implementations of the dispersion interaction in model potentials are terminated at n = 6. Those implementations that do include higher order contributions commonly only include even power terms, despite the fact that odd power terms can be important. Because the effective fragment potential (EFP) met...

Dispersion forces are long-range interactions between polarizable objects that arise from fluctuations in the electromagnetic field between them. Dispersion forces have been observed between microscopic objects such as atoms and molecules (the van der Waals interaction), between macroscopic objects (the Casimir interaction) and between an atom and a macroscopic object (the Casimir-Polder intera...