The photoluminescence features of Eu(3+)-, Tb(3+)-, Tb(3+)/Eu(3+)-alginate aerogel (hydrogel and alcogel) and Eu(3+)-alginate xerogel hybrids were investigated. The Eu(3+)-alginate aerogel and alcogel exhibit the highest (5)D0 quantum efficiencies (9.9 and 8.2%, respectively), while the hydrogel and xerogel have lower values (5.2 and 5.6%, respectively). The Tb(3+)/Eu(3+) hybrids are multiwavel...

Recreational use of alkaloid free-base cocaine, also known as crack cocaine, has reached epidemic proportions in the United States. Inhalation of crack cocaine is known to cause a variety of pulmonary complications. Herein we present a case of diffuse alveolar hemorrhage (DAH) and particulate foreign matter deposition in the setting of crack cocaine inhalation.

the aim of this work is to synthesize and investigate the performance of yttria-doped zirconia solgelcoatings in the chemical corrosion prevention of zircaloy-4 (zirconium alloy) in a 1 n h2so4environment. the influence of four different molar ratios of water to alkoxide, namely 1, 4, 12, and20, on the coating quality and its corrosion prevention performance was investigated. differentialtherma...

Previous work has shown that organosilica-based xerogels have the potential to control biofouling. In this study, modifications of chemistry were investigated with respect to their resistance to marine slimes and to settlement of barnacle cyprids. Adhesion force measurements of bovine serum albumin (BSA)-coated atomic force microscopy (AFM) tips to xerogel surfaces prepared from aminopropylsily...

Laser effects have been obtained with dye-doped hybrid xerogel samples prepared several years ago and stored in different "classical" conditions. Firstly, using the same configuration of the laser cavity as was used 4-5 years ago, we have obtained almost identical laser performances, and slope conversion efficiencies were measured up to 80% and operational lifetimes, with 1-mJ initial output en...

A series of molecular dynamics simulations using the embedded atom method is conducted to investigate crack propagation under mode I loading in a Ni single crystal with and without defects. The crack system (0 0 1)[1 0 0] in a slab of 160 000 atoms was studied. Defects consisting of lines of vacancies were introduced near the crack tip. Critical loads and strain energy distributions around the ...

In this paper, elasto-plastic analysis of an edge crack has been performed using element free Galerkin method. A model problem has been solved in plane stress condition under mode-I loading. A system of nonlinear equations has been obtained by using incremental theory of plasticity, and the equations are solved by assuming piecewise linear approximation. A code has been written in Matlab for el...

There are many ways that women support their use of crack cocaine, including sex-for-crack bartering and other forms of prostitution. Empirical studies conducted in the mid-1970s and in the mid-1980s in New York City, and in Chicago in the late 1980s to early 1990s are compared, analyzing similarities and differences between the contemporary crack-prostitution scene and previous prostitution sc...

This paper is concerned with the problem of plastic zone at the tip of an edge crack in an isotropic elastoplastic strip under anti-plane deformations. By means of complex potential and Dugdale model, the stress intensity factor and the size of plastic zone are obtained in closed-form. Furthermore, the analytic solutions for an edge crack at the free boundary of a half-space and a semi-infinite...

A new experimental method, called the 'hole filling method', is proposed to simulate the healing of internal cracks in rolled workpieces. Based on the experimental results, the evolution in the microstructure, in terms of diffusion, nucleation and recrystallisation were used to analyze the crack healing mechanism. We also validated the phenomenon of segmented healing. Internal crack healing inv...