The preparation of cationic water-soluble gallium phthalocyanine derivatives are described for the first time. Peripheral and nonperipheral 3-hydroxypyridine tetrasubstituted gallium(III)phthalocyanines (5a, 6a) and their quaternarized derivatives (5b and 6b) have been synthesized and characterized by elemental analysis, IR, H NMR spectroscopy, electronic spectroscopy and mass spectra. The quat...

The present study describes a two-step synthesis process for the cobalt complex of tetra-2,3-(5,6-di-tert-butyl-pyrazino) porphyrazine (tBu-TPyzPzCo). product was ultrasonically impregnated onto carbon black (CB) to prepare supported catalyst (tBu-TPyzPzCo/CB). We built split photoelectric catalytic device test performance photocatalytic, electrocatalytic and photoelectrocatalytic degradation p...

Crystalline microporous materials are solids formed by interconnected pores of less than 2 nm in size. Typically, they possess large surface areas desirable for versatile applications such as catalysis, gas adsorption, and energy storage. In the present work, we propose a new porphyrin-based 2D nanoporous crystal, named Porphyrazine (2DP), which is topological assembling H$_{5}$C$_{13}$N$_{4}$ ...