ABSTRACT In this work, the dry reforming of methane was studied using a corona and glow discharge plasma microreactors. A chemical kinetic model was developed to understand the reaction better. The modelization allowed prediction of the reactants conversion according to the energy transfer to the gas (P×τ). The β value is trait of the energy cost, whatever this value was leeser indicated ...

Three conventional and novel hydrogen and liquid fuel production schemes, i.e. steam methane reforming (SMR), solar SMR, and hybrid solar-redox processes are investigated in the current study. H2 (and liquid fuel) productivity, energy conversion efficiency, and associated CO2 emissions are evaluated based on a consistent set of process conditions and assumptions. The conventional SMR is estimat...

Solid oxide fuel cells (SOFCs) can be operated in a reversed mode as electrolyzer cells for electrolysis of H2O and CO2. In this paper, a 2D thermal model is developed to study the heat/mass transfer and chemical/electrochemical reactions in a solid oxide electrolyzer cell (SOEC) for H2O/CO2 co-electrolysis. The model is based on 3 sub-models: a computational fluid dynamics (CFD) model describi...

Introduction The steam reforming of alcohols, particularly methanol and ethanol, presents a promising method of producing hydrogen. Due to its high activity at relatively low temperatures, Pd/ZnO has received attention as a methanol steam reforming (MSR) catalyst to produce H2 at very high CO2 selectivity. 1 Pd supported on most other materials dehydrogenates methanol to CO. Similarly, Co catal...

The reforming of pure ethanol was studied over a bi-metallic precious metal (Rh/Pt) catalyst deposited on a ceramic monolith in order to analyze reforming process conditions. High ethanol conversion tests performed at low space velocities (<20,000 h ) confirmed that the catalyst could achieve 100% ethanol conversion to equilibrium concentrations of H2, CO, CO2 and CH4. Low conversion tests at h...

Biogas, consisting of CH4 and CO2, is a promising energy source can be converted into H2 by dry reforming reaction. In this study, membrane reactor adopted to promote the performance biogas reforming. The aim study investigate effect pressure sweep gas on get H2. molar ratio supplied CH4:CO2 reaction temperature also investigated. It observed that impact psweep concentrations CO2 small irrespec...

TAP Investigations of the CO2 Reforming of CH4 over Pt/ZrO2 A. N. J. van Keulen,∗,†,1 K. Seshan,† J. H. B. J. Hoebink,‡ and J. R. H. Ross∗ ∗College of Science, University of Limerick, Limerick, Ireland; †Catalytic Processes and Materials Group, Faculty of Chemical Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands; and ‡Schuit Institute of Catalysis, Laboratorium ...

The activity of Ni supported on mesoporous SBA-15, MCM-41, KIT-6, and a sol-gel prepared Ni/γAl2O3, for catalysing methane dry reforming was investigated. The chemical and physical characteristics of the catalysts before and after catalytic testing were investigated using X-Ray diffraction, X-ray Photoemission Spectroscopy, Transmission Electron Microscopy, Scanning Electron Microscopy / Energy...

A highly active and stable nano structured Pt/Mg1-xNixO catalysts was developed by a simple co-precipitation method. The obtained Pt/Mg1-xNixO catalyst exhibited cubic structure nanocatalyst with a size of 50-80 nm and realized CH4 and CO2 conversions as high as 98% at 900°C with excellent stability in the dry reforming of methane. The characterization of catalyst was performed using various ki...

Co-processing of formic acid or carbon dioxide with CH4 (FA/CH4 = 0.01-0.03 and CO2/CH4 = 0.01-0.03) on Mo/H-ZSM-5 catalysts at 950 K with the prospect of kinetically coupling dehydrogenation and deoxygenation cycles results instead in a two-zone, staged bed reactor configuration consisting of upstream oxygenate/CH4 reforming and downstream CH4 dehydroaromatization. The addition of an oxygenate...