This paper has been presented at an expert meeting on CO2 capture technology learning at the IEA headquarters, January 24th 2003. The electricity sector is a key source of CO2 emissions and a strong increase of emissions is forecast in a business-as-usual scenario. A range of strategies have been proposed to reduce these emissions. This paper focuses on one of the promising strategies, CO2 capt...

Several reactions, known from other amine systems for CO2 capture, have been proposed for Lewatit R VP OC 1065. The aim of this molecular modeling study is to elucidate the CO2 capture process: the physisorption process prior to the CO2-capture and the reactions. Molecular modeling yields that the resin has a structure with benzyl amine groups on alternating positions in close vicinity of each ...

Reducing atmospheric CO2 using a combination of air capture and offshore geological storage can address technical and policy concerns with climate mitigation. Because CO2 mixes rapidly in the atmosphere, air capture could operate anywhere and in principle reduce CO2 to preindustrial levels. We investigate the Kerguelen plateau in the Indian Ocean, which offers steady wind resources, vast subsea...

CO2 capture and storage is a potential means to alleviate global warming and ocean acidification. Herein, CO2 capture with various functionalized graphanes and the effects of functional groups are investigated by density functional theory (DFT). Our results show that CO2 adsorbs weakly on a bare graphane sheet, and absorbs slightly better when functionalized with P-substituted graphane, and inc...

The role of carbon dioxide in global warming is one of the contemporary environmental issues and it is, therefore, necessary to have available technology to capture the released CO2 into the atmosphere. Amino acids have the same amine functionality as alkanolamines with similar behavior towards CO2 absorption. The solubility of carbon dioxide in potassium glycinate (KG) solutions with different...

Nanoparticle organic hybrid materials (NOHMs) have been recently developed that comprise an oligomeric or polymeric canopy tethered to surface-modified nanoparticles via ionic or covalent bonds. It has already been shown that the tunable nature of the grafted polymeric canopy allows for enhanced CO2 capture capacity and selectivity via the enthalpic intermolecular interactions between CO2 and t...

Liquid amines can be immobilized within the pores of polymeric supports to provide a regenerable CO2 sorbent. This paper describes the capture of CO2 by a range of ethanolamines (primary, secondary, and tertiary) immobilized within the pores of high-surface-area poly(methyl methacrylate) beads. These supported amines were used to remove low concentrations (7.6 mmHg) of CO2 by a pressure swing a...