Mots-clés: adsorption de CO2, thermographie IR, spectroscopie DRIFT, méthodologie haut-débit, modélisation thermique, chaleur d'adsorption, technique inverse. Abstract: CO2 capture via adsorption process on porous materials (adsorbents) is a promising alternative due to its high selectivity and low energy penalties. We have investigated in-situ CO2 adsorption on solid adsorbents by combining Di...

This study simulated the adsorption and separation of CO2 by metal-organic frameworks material M-MOF-74, established skeleton model M-MOF-74 series adsorbent, calculated pure component gas CO2/N2 mixed on MMOF- 74 adsorbent grand canonical Monte Carlo method. Among performances MOF-74 materials with metal centers Mg, Co, Ni, Zn, Mg-MOF-74 had highest capacity, selection coefficient heat. When w...

A commercial activated carbon supplied by Norit, R2030CO2, was evaluated as CO2 adsorbent under conditions relevant to post-combustion CO2 capture (ambient pressure and diluted CO2). It has been demonstrated that this carbon possesses sufficient CO2/N2 selectivity in order to efficiently separate a binary mixture composed of 17 % CO2 in N2. Moreover, this carbon was easily completely regenerate...

Versatile odor sensors that can discriminate among huge numbers of environmental odorants are desired in many fields, including robotics, environmental monitoring, and food production. However, odor sensors comparable to an animal's nose have not yet been developed. An animal's olfactory system recognizes odor clusters with specific molecular properties and uses this combinatorial information i...

Carbonaceous material (brown coal) modified by pyrolysis, activation, and enrichment in nitrogen, with two different factor reagents, have been used as adsorbent of phenol from liquid phase. Changes in the phenol content in the test solutions were monitored after subsequent intervals of adsorption with selected adsorbents prepared from organic materials. Significant effect of nitrogen present i...

The H2/CO2 gas separation is extremely emerging both for the production of H2 which useful as an energy source/fuel due to high content per unit weight and capturing CO2 emissions that cause global warming climate change. adsorption method has come fore because it requires less process than other technologies a reduced environmental impact. In order determine promising adsorbent, really time-co...

As the fossil fuels kept on depleting, intense research in developing hydrogen (H2) as the alternative fuel has been done to cater our tremendous demand for fuel. The potential of H2 as the ultimate clean fuel differs with the fossil fuel that releases significant amounts of carbon dioxide (CO2) into the surrounding and leads to the global warming. The experimental work was carried out to study...

A series of polyethyleneimine (PEI) incorporated MIL-101 adsorbents with different PEI loadings were reported for the first time in the present work. Although the surface area and pore volume of MIL-101 decreased significantly after loading PEI, all the resulting composites exhibited dramatically enhanced CO2 adsorption capacity at low pressures. At 100 wt% PEI loading, the CO2 adsorption capac...

Three kinds of inorganic alkali are introduced into tetraethylenepentamine (TEPA)and polyethyleneimine (PEI)-modified MCM-41 as the CO2 adsorbents. FT-IR and TGA are used to characterize the surface groups and the thermal stability of adsorbents. Chemical titration method is used to measure the alkali amounts of adsorbents. Thermo-gravimetric analysis with 10% CO2/90% N2 as the simulated flue g...