نتایج جستجو برای: co ii ion

تعداد نتایج: 1076501  

Journal: :The Journal of biological chemistry 1990
M L Brader N C Kaarsholm M F Dunn

The cobalt(II)-substituted proinsulin and insulin hexamers have been studied in solution via electronic absorption spectroscopy. Hexameric proinsulin is shown to undergo the phenol-induced T6 to R6 conformational transition in a manner analogous to that previously established for insulin. In the absence of coordinating anions, the coordination spheres of the Co(II) ions in the proinsulin and in...

2009
Vaibhave Aggarwal Sujata Kashyap Udai P. Singh

Some heterobimetallic ion-pair complexes of Ni(II) with Mn(II), Co(II) and , Zn (II) using 1,10-phenanthroline (phen) and 1-tert-butylimidazole-2-thione (tm) ligands were prepared by co-crystallization of Ni(II)-phen cationic complex and Cl / tm containing anionic complex in acetonitrile / methanol solvent. The [Ni(phen)3][MnCl4] (1) contains two molecule of acetonitrile and [Ni(phen)3] 2+ is h...

2016
Jamshid M. Ashurov Nodira J. Obidova Hudaybergen B. Abdireymov Bakhtiyar T. Ibragimov

The reaction of 2-(2-oxo-2,3-di-hydro-1,3-benzo-thia-zol-3-yl)acetic acid (NBTA) and tri-ethano-lamine (TEA) with Co(NO3)2 results in the formation of the title complex, [Co(C6H15NO3)2](C9H6NO3S)2, which is formed as a result of the association of bis-(tri-ethano-lamine)-cobalt(II) and 2-(2-oxo-2,3-di-hydro-1,3-benzo-thia-zol-3-yl)acetate units. It crystallizes in the monoclinic centrosymmetric...

2015
Samia Benmansour Smail Triki Carlos J. Gómez-García Melanie Pilkington

Three new compounds have been synthesized and characterized with Fe(II), Co(II) and Mn(II), the polynitrile anionic ligand 1,1,3,3-tetracyano-2-(3-hydroxypropoxy)-propenide (tcnopr3OH ́) and the co-ligand 4,41-bipyridine (4,41-bpy). The Fe(II) compound, formulated as [FeII(tcnoprOH)2(H2O)2(4,41-bpy)2] (1), contains monomeric complexes where the Fe(II) ion is coordinated to two trans polynitrile ...

2013
Fatiha Guenifa Ouahida Zeghouan Nasreddine Hadjadj Lamia Bendjeddou Hocine Merazig

The title layered polymer, [Co(N3)2(C7H10N2)2] n , contains Co(II), azide and 4-(dimethyl-amino)-pyridine (4-DMAP) species with site symmetries m2m, 2 and m, respectively. The Co(2+) ion adopts an octa-hedral coordination geometry in which four N atoms from azide ligands lie in the equatorial plane and two 4-DMAP N atoms occupy the axial positions. The Co(II) atoms are connected by two bridging...

پایان نامه :دانشگاه آزاد اسلامی - دانشگاه آزاد اسلامی واحد تهران مرکزی - دانشکده علوم پایه 1390

چکیده در این مطالعه، اسپکتروفوتومتری و تشکیل کمپلکس بین سایمتیدین و کلرید مس (ii)، کلرید پالادیوم (ii) و نیترات کبالت (ii) و هم چنین اسپکتروفوتومتری داروی سایمتیدین با معرف پیروکتکول بنفش بررسی می شود. در رابطه با اسپکتروفوتومتری و تشکیل کمپلکس بین سایمتدین وکلرید مس (ii) ، کلرید پالادیوم (ii) و نیترات کبالت(ii) اطلاعات واکنش های کمپلکس به وسیله روش های اسپکتروفوتومتری در دماهای متفاوت با روش...

2014
John Vakros Kyriakos Bourikas Christos Kordulis Alexis Lycourghiotis

The mode of retention of Co(H2O)6 species at the “γ-alumina/aquatic solution” interface is refined using simulations, adsorption isotherm, potentiometric mass titrations and mainly proton ion titrations jointly with diffuse reflectance spectroscopy. It was found that the increase in the Co(II) surface concentration affects considerably the kind of the Co(II) species deposited. Mononuclear/mono-...

2011
Volkan EYUPOGLU Recep Ali KUMBASAR Volkan Eyupoglu

In this study, a zinc plant purification cake (CINKUR Co. Turkey) was leached with sulphuric acid and an acidic leach solution containing Zn(II), Fe(II), Pb(II), Al(III), Cu(II), Co(II) and Ni(II) ions was obtained. After purification, ammonium thiocyanate and water were added to the remaining leach solution containing Co(II) and Ni(II) ions to adjust the chemical media and ion concentration. T...

Journal: :Chemical communications 2005
Karena W Chapman Peter D Southon Colin L Weeks Cameron J Kepert

The family of dehydrated nanoporous Prussian Blue analogues, M(II)3[Co(III)(CN)6]2 (M(II) = Mn, Fe, Co, Ni, Cu, Zn, Cd), which contain coordinatively unsaturated divalent metal cations, undergoes reversible sorption of hydrogen gas up to 1.2 wt% (at 77 K, 101.3 kPa), the capacity of which depends on the metal ion.

2014
Frankie White Richard E. Sykora

The title compound, [Co(C15H11N3)(H2O){Pt(CN)4}] n , is a one-dimensional coordination polymer formed under hydro-thermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octa-hedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. The compound contains twofold rotation symmetry about its Co(II) ion, ...

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