Solid oxide fuel cells are high temperature electrochemical devices for direct conversion of fuel and oxidant to electricity and heat. The high temperature and dual atmosphere creates challenges for the materials in solid oxide fuel cell stacks. In this thesis SOFC stack materials were studied and developed. SOFC stacks are assembled at room temperature, then heated up, conditioned and operated...

Auger Electron Spectroscopy (AES) has been used to study the surface compositions of three types of nickel based chromium alloys. These alloys are IN600, IN601 and C22. AES analysis indicated the presence of chromium and oxygen on their surfaces. The formation of this chromium oxide surface layer, 3 nm thick, provides excellent corrosion resistance. For alloy C22, no molybdenum was indicated on...

The transport processes in chromium oxide reviewed here, are related to the basic ionic processes in oxides. Solid state science has been effective in describing the complicated diffusion-controlled oxide growth of chromium and chromia-forming alloys. Additions of reactive elements to chromia-forming alloys have a remarkably beneficial effect and this effect is also related to ionic transport p...

Vanadium is an important metal used almost exclusively in ferrous and non-ferrous alloys due to its physicochemical and mechanical properties such as grain refinement, high tensile strength, hardness and fatigue resistance; it has a wide range of uses in the metallurgical and chemical sectors [1–3]. There are mainly three kinds of raw materials, bone coal, vanadium slag and waste vanadium catal...

The interaction of chromium oxide with different titania-silica supports has been examined. The oxide supports investigated consisted of SiO,, TiO, , physical mixtures of TiO, and SiO,, a surface titania overlayer on SiO, (10% of theoretical monolayer) and a surface silica overlayer on TiO, (80% of theoretical monolayer). The supported chromium oxide catalysts were structurally characterized wi...

Chromium oxide (α-Cr2O3) thin films were prepared using thermal annealing of chromium (Cr)films deposited on quartz substrates by direct current (DC) magnetron sputtering. The annealingprocess of the films was performed for different times of 60, 120,180 and 240 min. The influenceof annealing time on structural, morphological and optical properties of the prepared films wasinvestigated by diffe...

In this study adsorption of Cr(VI) from aqueous solution by Fe3O4 nanoparticles was investigated. Desorption process and recovery of nanoparticles using different solutions were then carried out, and it was observed that NaOH (0.5M) can remove 90% of adsorbed chromium ions. Following the completion of adsorption/ desorption cycles, it was determined that nanoparticles have still had a high abil...

Cathodic activation examined with reference to the cold fuslon developments (controversy). Historically cathodic activation has been used for plating preparation of p a s s i v e (o x i d e) s u r f a c e s e.g. nickel/chromium alloys, niobium and powdered metals. More recent results of work employing cathodic activation for preparing aluminum for plating will be presented e.g. process paramete...

Potentially toxic elements (PTEs) including nickel and chromium are often present in soils overlying basalt at concentrations above regulatory guidance values due to the presence of these elements in underlying geology. Oral bioaccessibility testing allows the risk posed by PTEs to human health to be assessed; however, bioaccessibility is controlled by factors including mineralogy, particle siz...

Tin oxide thin film deposited on to glass substrates by the process of DC reactive magnetron sputtering has been used in our work. These films were characterized for their thermoelectric behavior. Further, a novel method has been developed to enhance the Seebeck coefficient of these films. Prior to the oxide film deposition on the glass substrate, thin metal films have been deposited at the two...