In this work In2S3 and CdS nanoparticles were prepared by a simple hydrothermal method and then annealed at 500 °C for 2 h in an Ar gas until CdIn2S4(CdIS)-CdS nanocomposites were formed. Afterwards, efficiency of the as-synthesized CdIS-CdS nanocomposite in quantum dot-sensitized solar cells (QDSSCs) was evaluated. For this purpose, the as-prepared CdIS-CdS nanocomposites were deposited on TiO...

Cadmium sulfide (CdS) is a unique semiconductingmaterial for solar hydrogen generation applications with a tunable, narrowbandgap that straddles water redox potentials. However, its potential towards efficient solar hydrogen generation has not yet been realized due to low photon-tocurrent conversions, high charge carrier recombination and the lack of controlled preparation methods. In this work...

Abstarct: Nanostructured colloidal semiconductors with heterogeneous photocatalytic behavior have drawn considerable attention over the past few years. This is due to their large surface area, high redox potential of the photogenerated charge carriers, and selective reduction/oxidation of different classes of organic compounds. In the present paper, we have carried out a systematic synthesis of...

Selective activation of primary C-H bonds for fine chemicals synthesis is of crucial importance for the sustainable exploitation of available feedstocks. Here, we report a viable strategy to synthesize ternary GR-CdS-TiO2 composites with an intimate spatial integration and sheet-like structure, which is afforded by assembling two co-catalysts, graphene and TiO2, into the semiconductor CdS matri...

Coupling light-harvesting semiconducting nanoparticles (NPs) with redox enzymes has been shown to create artificial photosynthetic systems that hold promise for the synthesis of solar fuels. High quantum yields require efficient electron transfer from the nanoparticle to the redox protein, a property that can be difficult to control. Here, we have compared binding and electron transfer between ...

This review focuses on our research findings about efficiency of different nano materials synthesized by us for photocatalytic hydrogen production from industrial wastes. Lab-scale reactors were fabricated liquid phase alkaline waste streams and gaseous sulfide. The effects operating parameters namely pH, flow rate, light intensity, depth, sulfide sulphite concentration investigated 7 photocata...

We report on the fabrication of PbS-CdS (core-shell) quantum dot (QD)-sensitized solar cells by direct adsorption of core-shell QDs on mesoporous TiO2 followed by 3-mercaptopropionic acid ligand exchange. PbS-CdS QD-sensitized solar cells show 4 times higher efficiency with respect to solar cells sensitized with PbS QDs. The significantly enhanced mean electron lifetime and electron diffusion l...

This work focuses on preparing TiO2, CdS, and composite TiO2:CdS thin films for photovoltaic applications by thermal evaporation. The suggested materials exhibit very good optical electrical properties can play a significant role in enhancing the efficiency of device. Various microscopy spectroscopy techniques were considered to investigate optical, morphological, photoluminescence, properties....

The photoelectrochemical properties of nanoheterostructures based on the wide band gap oxide substrates (ZnO, TiO2, In2O3) and CdS nanoparticles deposited by the successive ionic layer adsorption and reaction (SILAR) method have been studied as a function of the CdS deposition cycle number (N). The incident photon-to-current conversion efficiency (IPCE) passes through a maximum with the increas...