In this work, we present the application of exergy analysis in the evaluation of the ethanol steam reforming (ESR) process in a catalytic membrane reactor (CMR) containing Pd-Ag membranes sandwiched by PdRh/CeO2 catalyst to produce fuel cell grade pure hydrogen (no sweep gas). ESR experiments were performed at T=873-923 K and P=4-12 bar. The fuel was a mixture of ethanol and distilled water wit...

The intrinsic kinetics and diffusion behaviour of methane steam reforming have been investigated in this work. Measurements of effective diffusivities of the gases present in methane steam reforming have been carried out by using the steady-state technique over wide ranges of temperature and pressure in a modified Wicke-Kallenbach (W-K) type diffusion apparatus. The effects of diffusion limitat...

Dry reforming of methane (DRM) has been investigated under an electronactivated catalytic bed in a thermo-electrical reactor. The main objective of this work was to investigate what the impact of the electrical current on the conversion of methane is. The combination of thermal and electrical energy allowed achieving higher conversions for both reactants at temperatures varying from 850–950°C. ...

A series of Ni/SBA-15/Al(2)O(3)/FeCrAl metal monolithic catalysts with Ni loadings varying between 3 % and 16 % were prepared, and their structure was characterized by various techniques. The catalytic activity of the catalyst for methane reforming with CO(2) leading to synthesis gas was evaluated using a fixed-bed reactor. The results indicate good catalytic activity of the Ni/SBA-15/Al(2)O(3)...

An ultra-high vacuum (UHV) setup for "real" and "inverse" model catalyst preparation, depth-resolved near-surface spectroscopic characterization, and quantification of catalytic activity and selectivity under technologically relevant conditions is described. Due to the all-quartz reactor attached directly to the UHV-chamber, transfer of the catalyst for in situ testing without intermediate cont...

The integration of mixed ionic electronic conducting (MIEC) membranes for air separation in a small-to-medium scale unit for H2 production (in the range of 650-850 Nm3/h) via auto-thermal reforming of methane has been investigated in the present study. Membranes based on mixed ionic electronic conducting oxides such as Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) give sufficiently high oxygen fluxes at temp...

Due to high applicability of the fixed bed catalytic naphtha reforming reactors, hydrodynamic features of this kind of reactors with radial flow pattern are improved in this work by utilising computational fluid dynamics technique. Effects of catalytic bed porosity, inlet flow rate and flow regime through the bed on the flow distribution within the system are investigated.It is found that t...

Bio-ethanol reforming was studied using a plasma-catalytic reactor for hydrogen production at low temperature and atmospheric pressure without diluent gas or external heating. The plasma applied was a DC pulse discharge (corona) plasma. The water gas shift (WGS) catalyst was put just below the cathode electrode. The discharge generated heat was effectively used for feed vaporization and theWGS ...