To understand the effect of different thermal conductivities on catalytic combustion characteristics, effect of thermal conductivity on micro-combustion characteristics of hydrogen-air mixtures in Pt/γ-Al2O3 catalytic micro-combustors were investigated numerically with detailed chemical kinetics mechanisms. Three kinds of wall materials (100, 7.5, and 0.5 W/m·K) were selected to investigate the...

to improve the photo-catalytic degradation of salicylic acid, we reported the fabrication of ordered tio2 nanotube arrays by a simple and effective two-step anodization method and then these tio2 nanotubes treated in a methanol solution under uv light irradiation. the tio2 nanotubes prepared in the two-step anodization process showed better photo-catalytic activity than tio2 nanotubes prepared ...

CO2 reforming of methane (CRM) over unpromoted and potassium promoted Ni/Al2O3 catalysts was studied. The catalysts were prepared by impregnation method and characterized by X-ray diffraction (XRD), N2 adsorption (BET), temperature programmed reduction (TPR), temperature programmed oxidation (TPO) and scanning electron microscope (SEM) techniques. The obtained results showed that addition of K2...

the catalytic oxidation of toluene over copper oxide supported on natural diatomite was investigated. the catalyst was prepared by the wet impregnation method and characterized by using the brunauer emmett teller (bet), field emission scanning electron microscopy (fesem), x-ray diffraction (xrd), x-ray fluorescence (xrf) and temperature-programmed reduction (tpr) analysis. the highest catalytic ...

Nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. Factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents.  This nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. The prepared sulfated titania s...

A catalytic spectrophotometric method for determination of ultra-trace quantities of manganese(II) id described. The method is based on the catalytic effect of manganese(II) on the oxidation reaction of ferroin by potassium periodate in acidic media. The reaction is monitored spectrophotometrically at 510 nm by a slope method and Mn(II) is determinable in the range of 1-1000ngmL-1</sup...

A two-dimensional nanolayered polyoxomolybdate, [4,4´-H2bipy] [Mo7O22].H2O (1), where 4,4´-bipy = 4,4´-bipyridine, was prepared and characterized by FT-IR and atomic absorption spectroscopies, transmission electron microscopy (TEM), X-ray single crystal and powder diffraction (XRD), and thermogravimetric analysis. The catalytic performance of 1 was assessed in the epoxidation of some olefins em...

Nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. Factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents.  This nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. The prepared sulfated titania s...

a simple, rapid and sensitive method has been developed for determination of traces of tellurium (iv) (7.0-120.0 ng/ml) based on it’s catalytic effect on the reduction reaction of lauth’s violet by sulfide ion at ph 4.2. the reaction is monitored spectrophotometrically by measuring the decrease in absorbance of lauth’s viole at 600 nm by the fixed time method. the detection limit is 5.0 ng/ml a...