نتایج جستجو برای: carbonates
تعداد نتایج: 9055 فیلتر نتایج به سال:
7.03.3 SOURCES AND DIAGENESIS OF SHOAL-WATER CARBONATE-RICH SEDIMENTS 75 7.03.3.1 Sources of Shoal-water Carbonates 75 7.03.3.1.1 General considerations 75 7.03.3.1.2 Sources of carbonate muds 76 7.03.3.1.3 Formation of carbonate sands 76 7.03.3.2 Early Marine Diagenesis of Shoal-water Carbonate-rich Sediments 77 7.03.3.2.1 Pore-water chemistry 77 7.03.3.2.2 Precipitation of early carbonate cem...
A novel metal-free approach to construct the tetrasubstituted furans from Morita-Baylis-Hillman (MBH)-carbonates of acetylenic aldehydes has been developed. This strategy involves the cascade nucleophilic substitution/5-exo-dig-cycloisomerization of MBH-carbonates with 1,3-dicarbonyl compounds to give uniquely substituted 2-furan-3-yl acrylates. Additionally, the obtained furan adducts open a n...
The use of different ligands allows the preparation of either allyl- or alkenylboronates by Pd-catalyzed borylation of allylic carbonates containing alkyne groups. Unprecedented borylative cyclisation to alkenylboronates takes place with PCy3. The difficult dissociation of NHC ligands allows borylation of carbonates in the presence of alkynes. Oxidation, regioselective Suzuki coupling, as well ...
Carbonates of the Ojo Huelos Member of the San Pedro Arroyo Formation include ostracodal limestones, brecciated micritic limestones, vuggy, mottled limestones, peloidal graistones/packstones, pisolitic rudstones and nodular limestones. These lithofacies record deposition in lacustrine, palustrine and alluvial environments. Lacustrine (ostracodal) limestones are isotopically heaviest, with nodul...
The mineralogical characterization of Mars by different exploration missions, provides a new image of the earliest conditions that prevailed on the planet surface. The detection of extensive deposits of phyllosillicates has been considered to be as a result of the production of hydrated silicates through alteration and precipitation under neutral to sub-alkaline conditions. Although extensive d...
The presence of carbonates in inclusions in diamonds coming from depths exceeding 670 km are obvious evidence that carbonates exist in the Earth's lower mantle. However, their range of stability, crystal structures and the thermodynamic conditions of the decarbonation processes remain poorly constrained. Here we investigate the behaviour of pure iron carbonate at pressures over 100 GPa and temp...
Biosignature analysis of cold seep carbonates T. Leefmann et al.
The cycling performance and SEI composition of Si nano-particle anodes in electrolytes containing 5–25 wt% fluoroethyelene carbonate (FEC) and 3–6 wt% vinylene carbonate (VC) has been investigated by a combination of by electrochemical cycling, electrochemical impedance spectroscopy, IR-ATR and XPS. The incorporation of FEC or VC changes the cycling performance, impedance, electrode morphology,...
This work has been undertaken in order to obtain data on thermodynamic properties of organic carbonates and to revise the group-additivity values necessary for predicting their standard enthalpies of formation and enthalpies of vaporization. The standard molar enthalpies of formation of dibenzyl carbonate, tert-butyl phenyl carbonate, and diphenyl carbonate were measured using combustion calori...
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