Measurements of electrochemical (EC) arsenite oxidation demonstrated thatthe arsenite oxidation current increased in the presence of carbonate while the potential of the onset of EC arsenite oxidation exhibited a strong shift toward less positive values. Examination of pH and total carbonate concentration effects on the EC arsenite oxidation parameters showed that they were affected solely by t...

Increasing atmospheric carbon dioxide (CO2) through human activities and invasion of anthropogenic CO2 into the surface ocean alters the seawater carbonate chemistry, increasing CO2 and bicarbonate (HCO − 3 ) at the expense of carbonate ion (CO 3 ) concentrations. This redistribution in the dissolved inorganic carbon (DIC) pool decreases pH and carbonate saturation state (). Several components...

The cycling performance and SEI composition of Si nano-particle anodes in electrolytes containing 5–25 wt% fluoroethyelene carbonate (FEC) and 3–6 wt% vinylene carbonate (VC) has been investigated by a combination of by electrochemical cycling, electrochemical impedance spectroscopy, IR-ATR and XPS. The incorporation of FEC or VC changes the cycling performance, impedance, electrode morphology,...

Powders of sodium-carbonate co-substituted hydroxyapatite, having sodium content in the range of 0.25–1.5 wt.% with a 0.25 wt.% step, were prepared by a precipitation-solid state reaction route. Compacts of the powders were sintered in a CO2 flow (4 mL/min) at 1100 °C for 2 h. The sintered ceramics contained sodium and carbonate ions in the ranges of 0–1.5 wt.% and 1.3–6 wt.%, respectively, whi...

Carbonate anion exchange reactions with water in the uranyl-carbonate and calcium-uranyl-carbonate aqueous systems have been investigated using computational methods. Classical molecular dynamics (MD) simulations with the umbrella sampling technique were employed to determine potentials of mean force for the exchange reactions of water and carbonate. The presence of calcium counter-ions is pred...

In this study, the non-catalytic supercritical method has been studied in utilizing dimethyl carbonate. It was demonstrated that, the supercritical dimethyl carbonate process without any catalysts applied, converted triglycerides to fatty acid methyl esters with glycerol carbonate and citramalic acid as by-products, while free fatty acids were converted to fatty acid methyl esters with glyoxal....

Pliocene and Pleistocene sediments from Sulu Sea ODP Sites 768 and 769 contain high-resolution records of pelagic sedimentation in a deep marine silled basin. Carbonate analyses reveal that both sites are free of pelagic carbonate up until 2.4 Ma, at which time carbonate becomes a major component of the pelagic marl sedimentation. The timing of this increase in calcium carbonate accumulation is...

Various concentrations of anionic surfactant, sodium dodecyl sulfate (SDS), were used to control the growth of calcium carbonate crystals. The obtained calcium carbonate particles were characterized by Fourier transform infrared spectrometry (FT-IR), X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM), laser scattering particle size analyzer and zeta potential analyzer...

The present paper compiles an up-to-date taxonomic inventory of dasycladalean green algae of the KimmeridgianEarly Berriasian Plassen Carbonate Platform and their resediments in basinal sediments (e.g., Barmstein Limestone, Sillenkopf Formation) of the Northern Calcareous Alps of Austria (p.p. Germany). Today, the Plassen Carbonate Platform sensu lato (or Plassen Group) is divided into three in...

Controlling the growth of the polymorphs of calcium carbonate is important in understanding the changing environmental conditions in the oceans. Aragonite is the main polymorph in the inner shells of marine organisms, and can be readily converted to calcite, which is the most stable polymorph of calcium carbonate. Both of these polymorphs are significantly more stable than vaterite, which is th...