A three-dimensional reconstruction of a nano-scale aqueous object can be achieved by taking a series of transmission electron micrographs tilted at different angles in vitreous ice: cryo-Transmission Electron Tomography. Presented here is a novel method of fine alignment for the tilt series. Size-selected gold clusters of ~2.7 nm (Au₅₆₁±₁₄ ), ~3.2 nm (Au₉₂₃± ₂₂ ), and ~4.3 nm (Au₂₀₅₇±₄₅) in dia...

In hypercholesterolemia, impaired nitric oxide activity has been associated with increased nitric oxide degradation by oxygen radicals. Deficiency of tetrahydrobiopterin, an essential cofactor of nitric oxide synthase, causes both impaired nitric oxide activity and increased oxygen radical formation. In this study we tested whether tetrahydrobiopterin deficiency contributes to the decreased nit...

Ultraviolet waves, because of their short wavelength, have a high energy and considerable damaging effects on surfaces. Protection against ultraviolet radiations is one of the finishing treatments done on surfaces exposed to sunlight. The importance of this issue in relation to human health, due to complications such as skin burns and cancer, is doubled. Up t...

the effects of confinement in carbon nanotubes on fischer-tropsch (ft) activity, selectivity and lifetime of carbon nanotubes (cnts) supported iron catalysts are reported. a method was developed to control the position of the catalytic sites on either inner or outer surface of carbon nanotubes. tem analyses revealed that more than 80% of iron oxide particles can be controlled to be positioned a...

Two novel phosphoryl-bridged bis- and tris(beta-cyclodextrin)s of different tether lengths, i.e., bis[m-(N-(6-cyclodextryl)-2-aminoethylaminosulfonyl)phenyl]-m-(chlorosulfonyl)phenylphosphine oxide (5) and tris[m-(N-(6-cyclodextryl)-8-amino-3,6-diazaoctylaminosulfonyl)phenyl]phosphine oxide (6), have been synthesized by reactions of 6-oligo(ethylenediamino)-6-deoxy-beta-cyclodextrins with tris[...

A pillar[6]arene with mono(ethylene oxide) groups was synthesized and it formed a highly stable inclusion complex with diquat, while the pillar[5]arene analogue did not.

Carbon dioxide capture and use as a carbon feedstock presents both environmental and industrial benefits. Here we report the discovery of a hybrid oxide catalyst comprising manganese oxide nanoparticles supported on mesoporous spinel cobalt oxide, which catalyses the conversion of carbon dioxide to methanol at high yields. In addition, carbon-carbon bond formation is observed through the produc...

Carbon oxide gaseous species are potentially considered as pollutants of the atmosphere of earth; especially, carbon monoxide and carbon dioxide which are of the well-known carbon oxids, play an effective role in the greenhouse gas emissions. Moreover, these species could initiate or handle some chain reactions in the troposphere that lead to emergence of some secondly air pollutants which may ...