The influence of calcination time on the phase transformation and crystallization kinetics of anodized titania nanotube arrays was studied using in-situ isothermal and non-isothermal synchrotron radiation diffraction from room temperature to 900 °C. Anatase first crystallized at 400 °C, while rutile crystallized at 550 °C. Isothermal heating of the anodized titania nanotubes by an increase in t...

Nanosized copper aluminate (CuAl(2)O(4)) spinel particles have been prepared by a precursor approach with the aid of ultrasound radiation. Mono-phasic copper aluminate with a crystallite diameter of 17nm along the (311) plane was formed when the products were synthesized using Cu(NO(3))(2) x 6H(2)O and Al(NO(3))(3) x 9H(2)O as starting materials, with urea as a precipitation agent at a concentr...

A series of ZnO/Al2O3 mixed oxide samples with varying Zn/Al ratio is prepared by coprecipitation, ageing, drying, and calcination. Samples are investigated in the state after drying and calcination. The applied methods include X-ray diffraction, solid-state 27Al magic-angle spinning nuclear magnetic resonance spectroscopy, transmission electron microscopy and thermogravimetric experiments coup...

A numerical model coupling transient radiative, convective, and conductive heat transfer, mass transfer, and chemical kinetics of heterogeneous solid–gas reactions has been developed for a semitransparent, non-uniform, and non-isothermal particle undergoing cyclic thermochemical transformations. The carbonation–calcination reaction pair for calcium oxide looping is selected as the model cycle b...

Nanocrystalline ceria has been considered as support for carbon monoxide preferentially oxidation. In this study ceria was prepared by precipitation method and the effects of preparation conditions, such as pH of solution (8-10), aging time (1-12 hr), drying temperature (80-120 °C), calcination time (2-6 hr) and temperature (400-600 °C) were investigated on ceria synthesized powders properties....

Co-precipitated Cu-MgO catalysts were prepared and evaluated for the gas-phase hydrogenation of furfural. The effect of heating rate at the calcination step was studied by comparing the performance of three catalysts prepared via the same procedure but calcined at different heating rates. The results established that altering the heating rate could influence the structural properties of the cat...

There is an increasing interest in the application of photocatalytic properties for disinfection of surfaces, air, and water. Titanium dioxide is widely used as a photocatalyst, and the addition of silver reportedly enhances its bactericidal action. However, the synergy of silver nanoparticles and TiO(2) is not well understood. The photocatalytic elimination of Bacillus atrophaeus was examined ...

Two nanocrystalline palladium-supported tin oxide catalysts for water denitration were synthesized by a modified sol–gel technique using appropriate chloride precursors for both support and active phases, and citric acid to tune the rate of hydrolysis and condensation. The difference among sample preparation procedures refers to the moment of the noble metal loading to the support, as well as t...

Non-hollow In(2)O(3) particles with hexagonal rod- and disk-shapes are generated from the calcination of porous CPPs; however, elongated hexagon-, ellipsoid-, and rod-shaped hollow In(2)O(3) particles are formed from the calcination of non-porous CPPs.