نتایج جستجو برای: bridged systems
تعداد نتایج: 1189900 فیلتر نتایج به سال:
The enclosure of functional entities within a protective boundary is an essential feature of biological systems. On a molecular scale, free-standing capsules with an internal volume sufficiently large to house molecular species have been synthesized and studied for more than a decade. These capsules have been prepared by either covalent synthesis or self-assembly, and the internal volumes have ...
in this thesis, using concepts of wavelets theory some methods of the solving optimal control problems (ocps). governed by time-delay systems is investigated. this thesis contains two parts. first, the method of obtaining of the ocps in time delay systems by linear legendre multiwavelets is presented. the main advantage of the meth...
چکیده در این پایاننامه ابتدا فضاهای متریک فازی را به صورت مشاهدهگرایانه بررسی میکنیم. فضاهای متریک فازی و توپولوژی تولید شده توسط این متریک معرفی شدهاند. سپس بر اساس فضاهایی که در فصل اول معرفی شدهاند آشوب توپولوژیکی، مینیمالیتی و مجموعههای متقاطع در شیوههای مختلف بررسی شده- اند. در فصل سوم مفهوم مجموعههای جاذب فازی به عنوان یک مفهوم پایهای در سیستمهای نیم-دینامیکی نسبی، تعریف شده است. ...
A computational strategy to analyze the dynamics of coherent electron transfer processes in bridged systems, involving three or more electronic states, is presented. The approach is based on partitioning of the Hilbert space of the time independent basis functions in subspaces of increasing dimensionality, which allows us to easily check the convergence of the time dependent wave function. Vibr...
A new two-dimensional manganese(II) coordination polymer, [Mn(μ-DEP)(μ-Cl)(H2O)2]n (1) (DEP is diethyl phosphate), was prepared from the reaction of MnCl2.4H2O and TEP (TEP is triethyl phosphate) ligand in mixture of H2O/CH3OH (1:10) at 40 °C. Suitable crystals of this complex for crystal structure determination were obtained by slow evaporation of the produced colorless solution at room temper...
The first N-heterocyclic carbene (NHC)-catalyzed [3+4] cycloaddition of azomethine imines and enals is disclosed. Oxidative catalytic remote activation of enals affords 1,4-dipolarophile intermediates that react with 1,3-dipolar azomethine imines to generate dinitrogen-fused seven-membered heterocyclic products with high optical purities. Our approach also provides effective kinetic resolution ...
The N,N'-dimesitylene substituted o-phenylenediamine 1 reacts with Sn[N(SiMe(3))(2)](2) under formation of the monomeric N-heterocyclic stannylene 2, while the chiral N,N'-substituted o-phenylenediamine 3 reacts with E[N(SiMe(3))(2)](2) (E = Ge, Sn) under formation of the chiral germylene 4 and the chiral stannylene 5, respectively. X-Ray diffraction studies with both stannylenes demonstrated t...
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