The title two-component mol-ecular crystal [systematic name: 3-(dihy-droxy-boran-yl)benzoic acid-1,3-dimethyl-7H-purine-2,6-dione (1/1)], C(7)H(7)BO(4)·C(7)H(8)N(4)O(2), comprises theophylline and 3-carb-oxy-phenyl-boronic acid mol-ecules in a 1:1 molar ratio. In the crystal, mol-ecules are self-assembled by O-H⋯O and N-H⋯N hydrogen bonds, generating layers parallel to (-209). The layers are st...

Art and science become inevitably intertwined in our appreciation of nature's forms. This concept is demonstrated by the creative team responsible for the cover images of Nonlinear Dynamics, Psychology, and Life Sciences. Denis Weaire, Stefan Hutzler, Wiebke Drenckhan form a leading international collaboration with photographers Tim Durham and Michael Boran that explores the physics of bubble p...

The title compound, [1-(CH(3))(3)NCH(2)-1,2-C(2)B(10)H(11)](+)·I(-) or C(6)H(22)B(10)N(+)·I(-), was obtained by the reaction of (1,2-dicarba-closo-dodeca-boran-yl)dimethyl-methanamine with methyl iodide. The asymmetric unit contains two iodide anions and two (o-carboran-yl)tetra-methyl-ammonium cations. The bond lengths and angles in the carborane cage are within normal ranges, but the N-C(meth...

The title compound, C19H17BF3P {alternative name: triphen-yl[(tri-fluoro-boran-yl)meth-yl]phosphanium}, was formed by the reaction of tri-phenyl-phosphine with potassium iodo-methyl-tri-fluoro-borate. The mol-ecule features a nearly staggered conformation along the P-C bond and a less than staggered conformation along the C-B bond. In the crystal, weak C-H⋯F hydrogen bonds between the meta-phen...

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Abstract In den letzten Jahren hat sich die metallfreie organische Synthese unter Verwendung von Triarylboranen als Katalysatoren zu einem weit verbreiteten Forschungsgebiet entwickelt. Hier berichten wir über eine umfassende theoretische und experimentelle Studie für hochselektive N‐substituierten Pyrazolen durch Erzeugung Carbenium‐Ionen aus der Reaktion zwischen Arylestern Vinyldiazoacetaten...

"Adımlar'ın Hümanizma Anketi" başlığıyla dönemin entelektüellerinden görüşler alan Adımlar dergisinin 8. sayısının neredeyse tamamı hümanizma tartışmasını sonlandırmaya ayrılmıştır. İlk makalede, ankete katılan yazarların ilgili görüşlerine yer verilmiş, kavrayışları ortaya konmuştur. Dolayısıyla bu makalenin amacı, sayısında ve anketini sonlandıran tartışmaların betimlenmesidir. Çalışmanın böl...