We report results from experiments with a pseudo-one-dimensional Belousov-Zhabotinsky reaction that employs 1,4-cyclohexanedione as its organic substrate. This excitable system shows traveling oxidation pulses and pulse trains that can undergo complex sequences of propagation failures. Moreover, we present examples for i breathing pulses that undergo periodic changes in speed and size and ii ba...

A closed excitable pathway with one point-to-point connection is used to generate a rotating wave both in experiments using the photosensitive Belousov-Zhabotinsky system and numerically with an Oregonator reaction-diffusion model. By varying the excitability and geometrical properties of the medium, propagation can be made unidirectional or bidirectional, giving rise, respectively, to the exis...

Unstable concentration gradients inherent in traveling chemical waves can give rise to buoyancy-driven convection, altering the speed of the wave. When an excitable Belousov– Zhabotinsky reaction system is confined within a sufficiently narrow, vertical two-dimensional channel, convection arises at a symmetry-breaking bifurcation point. The observed linear rate of change of wave speed with the ...

The finite wavelength instability generates trigger and packet waves in an extended three-variable Brusselatortype model. The trigger waves account for experimentally observed stacking (shock) structures and acceleration of oncoming waves before collision observed in the Belousov-Zhabotinsky system. Packet waves exhibit specular reflection from surfaces. The mouth of a narrow tube connected to ...

Resonance regions similar to the Arnol'd tongues found in single oscillator frequency locking are observed in experiments using a spatially extended periodically forced Belousov-Zhabotinsky system. We identify six distinct 2:1 subharmonic resonant patterns and describe them in terms of the position-dependent phase and magnitude of the oscillations. Some experimentally observed features are also...

Finger on the pulse: in a system of two pulse-coupled Belousov-Zhabotinsky oscillators, introducing a time delay or increasing the coupling strength brings about novel dynamic features (see picture, the two oscillators are shown in different colors), such as reversal of the roles of excitatory and inhibitory coupling or fast anti-phase oscillation. These features are not observed in diffusively...

The control of spiral wave parameters by electric current was investigated in the Belousov-Zhabotinsky (BZ) reaction. It was found that the wavelength and the period of spiral waves increase by a factor of up to 3 with electric current (both dc and ac). Using this procedure spiral waves with a period higher than the period of medium bulk oscillations were observed. It was also found that hyster...

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Potentiometrie measurements with platinum and silver electrodes of Ag induced oscillations in the oxygen-inhibited excitable Belousov-Zhabotinsky system are reported. Calculations based on the Oregonator model lead to the conclusion that the platinum electrode's potential is composed of two contributions, the Ce(III)/Ce(IV) redox couple which dominates at low Ag flow rates and the contribution ...