Iodine is an essential micronutrient for human health. Its deficiency causes a number of functional and developmental abnormalities such as goitre. The limestone region of Derbyshire, UK was goitre-endemic until it declined from the 1930s and the reason for this has escaped a conclusive explanation. The present study investigates the cause(s) of goitre in the UK-Peak District area through an as...

Despite reported synergies between alumina rich supplementary cementitious materials (SCMs) and limestone, previous studies have focused on up to 5% limestone content. Slag hydration in the presence of 10% limestone is reported in this paper. Hydration was followed through chemical shrinkage, calorimetry, thermal analysis, electron microscopy and X-ray powder diffraction. The results show that ...

This experiment was conducted to evaluate the effects of single or multi-particle size limestone on the egg shell quality, egg production, egg quality and feed intake in laying hens. A total of 280 laying hens (ISA brown) were used in this 10-wk trial. Laying hens were randomly assigned to 4 treatments with 14 replications per treatment and 5 adjacent cages as a replication (hens were caged ind...

The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [Au(I) 8 ] core, and pentanuclear [Au(I) 4 M(I) ] (M=Cu, Ag) complexes is presented. The linear [Au(I) 4 ] complex undergoes C-H functionalization of carbonyl compounds under mild reaction conditions. In addition, [Au(I) 4 Ag(I) ] catalyzes the carbonylation of primary amines to form ure...

Reaction of a phosphane-decorated benzenedithiol (pbdtH2) with coinage metal salts furnished polynuclear complexes [M2(pbdtH)2] (M=AuI) or [cat][M5(pbdt)3] (cat=unipositive cation, M=AgI, CuI), which were characterized by analytical and spectroscopic techniques single-crystal X-ray diffraction studies. Furthermore, double salt an anion [Ag5(pbdt)3(PPh3)]− that proved unstable in solution was cr...

Because grains comprise the major portion of diets for finishing beef cattle, and grains contain little calcium, limestone is typically added to finishing diets at levels of .7 to more than 1% of the dry matter. Feedgrade limestone varies in quality and consistency, which could alter performance responses by finishing beef steers. Selection of superior sources of limestone and(or) treatment of ...

The submillimeter antennas of the Atacama Large Millimeter Array (ALMA) have specifications that are beyond the current state of the art in accurate reflector antenna technology. Considering that as many as 64 of these antennas would eventually be needed, the ALMA partners AUI/NRAO and ESO each agreed to acquire a prototype antenna, and subject these to an extensive evaluation program. In this ...

The incorporation of an N-heterocyclic carbene (NHC) moiety into a self-assembled MII4L6 cage framework required the NHC first to be metallated with gold(i). Bimetallic cages could then be constructed using zinc(ii) and cadmium(ii) templates, showing weak luminescence. The cages were destroyed by the addition of further gold(i) in the form of AuI(2,4,6-trimethoxybenzonitrile)2SbF6, which caused...

In recent, the placement of backfill in underground mines has emerged as a new paradigm in research as it not only improves safety but also allows disposal of byproducts including coal ash. In this regards, this paper addresses the backfilling challenges in limestone mine to prevent sinkhole and subsidence. Limestone mines, generally regarded as being safer than coal and metal mines, have been ...