A high-temperature procedure to hydrogenate diamond films using molecular hydrogen at atmospheric pressure was explored. Undoped and doped chemical vapour deposited (CVD) polycrystalline diamond films were treated according to our annealing method using a H2 gas flow down to ~50 ml∕min (STP) at ~850 °C. The films were extensively evaluated by surface wettability, electron affinity, elemental co...

Direct measurement of particle formation and growth from the oxidation of biogenic emissions T. M. VanReken, J. P. Greenberg, P. C. Harley, A. B. Guenther, and J. N. Smith Advanced Study Program, National Center for Atmospheric Research, Boulder, CO, USA Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, CO, USA Received: 23 May 2006 – Accepted: 27 May 2006 – Pub...

Early Palaeoproterozoic (2.5-2.0 billion years ago) was a critical phase in Earth's history, characterized by multiple severe glaciations and a rise in atmospheric O(2) (the Great Oxidation Event). Although glaciations occurred at the time of O(2) increase, the relationship between climatic and atmospheric transitions remains poorly understood. Here we report high concentrations of the redox-se...

Neoproterozoic (1,000-542 Myr ago) Earth experienced profound environmental change, including 'snowball' glaciations, oxygenation and the appearance of animals. However, an integrated understanding of these events remains elusive, partly because proxies that track subtle oceanic or atmospheric redox trends are lacking. Here we utilize selenium (Se) isotopes as a tracer of Earth redox conditions...

This manuscript describes a laboratory study on the photo-oxidation of indole under low-NOx conditions. Secondary organic aerosols (SOA) were chemically characterize to determine the importance of indole chemistry in the formation of brown carbon (BrC) constituents. State of art analytical techniques (high-resolution mass spectrometers) used is this study, provide novel and important insights i...

The products of the primary OH-initiated oxidation of toluene were investigated using the turbulent flow chemical ionization mass spectrometry technique under different oxygen, NO, and initial OH radical concentrations as well as a range of total pressures. The bicyclic peroxy radical intermediate, a key proposed intermediate species in the Master Chemical Mechanism (MCM) for the atmospheric ox...

The search for active catalysts that efficiently oxidize methane under ambient conditions remains a challenging task for both C1 utilization and atmospheric cleansing. Here, we show that when the particle size of zinc oxide is reduced down to the nanoscale, it exhibits high activity for methane oxidation under simulated sunlight illumination, and nano silver decoration further enhances the phot...

It is unclear why atmospheric oxygen remained trapped at low levels for more than 1.5 billion years following the Paleoproterozoic Great Oxidation Event. Here, we use models for erosion, weathering and biogeochemical cycling to show that this can be explained by the tectonic recycling of previously accumulated sedimentary organic carbon, combined with the oxygen sensitivity of oxidative weather...