The Taguchi design of experiments (DOE) approach is adopted here to evaluate the impact ofeffective factors such as nanoparticles type, nanoparticles to model solution mass ratio, asphaltenestructure, and temperature on asphaltene adsorption equilibrium. Herein, the toluene-asphaltenesolution model is applied. Three commercially nanoparticles (SiO2, Al2O3, and TiO2) are used.<...

The molecular properties of asphaltenes have been the subject of uncertainty in the literature; in particular the molecular architecture is still a matter of debate. Some literature reports provide evidence that the contrast of petroleum asphaltenes versus coal-derived asphaltenes is useful for understanding the governing principles of asphaltene identity. Here, we employ fluorescence correlati...

Asphaltene and smaller aromatic molecules tend to form linear nanoaggregates in bitumen. Over the years bitumen undergoes chemical aging and during this process, the size of the nanoaggregate increases. This increase is associated with an increase in viscosity and brittleness of the bitumen, eventually leading to road deterioration. This paper focuses on understanding the mechanisms behind nano...

We study chemical aging in "Cooee bitumen" using molecular dynamic simulations. This model bitumen is composed of four realistic molecule types: saturated hydrocarbon, resinous oil, resin, and asphaltene. The aging reaction is modelled by the chemical reaction: "2 resins → 1 asphaltene." Molecular dynamic simulations of four bitumen compositions, obtained by a repeated application of the aging ...

formation of asphaltene deposition during oil production, processing and synthesis is known as a fundamental problem of petroleum reservoir worldwide. asphaltene is a petroleum fraction that can lead to increasing the operating costs in these industries. variations in operational pressure, temperature and fluid composition are generally the significant cause of asphaltene precipitation. in this...

asphaltene instability is one of the major problems in gas injection projects throughout the world. numerous models have been developed to predict asphaltene precipitation; the scaling equation is an attractive tool because of its simplicity and not involving complex properties of asphaltene. in this work, a new scaling model is presented to account  for asphaltene precipitation due to gas inje...

Despite recent advances in spectroscopic techniques, there is uncertainty regarding the nature of the carbonyl groups in the asphaltene and resin fractions of crude oil, information necessary for an understanding of the physical properties and environmental fate of these materials. Carbonyl and hydroxyl group functionalities are not observed in natural abundance 13C nuclear magnetic resonance (...

In the current study, the kinetics of asphaltene particle flocculation is investigated under a shear flow through numerical simulation. The discrete element method (DEM) is coupled with computational fluid dynamics (CFD) to model the agglomeration and fragmentation processes. In addition, a coalescence model is proposed to consider the attachment of colliding particles. The changes in mean asph...

Formation of asphaltene deposition during oil production, processing and synthesis is known as a fundamental problem of petroleum reservoir worldwide. Asphaltene is a petroleum fraction that can lead to increasing the operating costs in these industries. Variations in operational pressure, temperature and fluid composition are generally the significant cause of asphaltene precipitation. In ...

Asphaltene instability is one of the major problems in gas injection projects throughout the world. Numerous models have been developed to predict asphaltene precipitation; The scaling equation is an attractive tool because of its simplicity and not involving complex properties of asphaltene. In this work, a new scaling model is presented to account  for asphaltene precipitation due to gas ...