The general equation of state which was found for dense fluids, both compressed liquids and dense supercritical fluids, namely "Linear Isotherm Regularity," is extended to the lower density range, specifically for densities lower than the Boyle density. This new equation of state which is called "ELIR" is shown to be compatible with the equations of state based on statistical-mechanical the...

A new simple model is introduced for a liquid and an equation of state is derived based on this model and the statistical mechanical calculations. This equation of state works well for the non-polar and slightly polar liquids. The important conclusion that may be deduced from this equation of state is that if the reduced variables of state are chosen and defined appropriately, then, the pri...

in this work, the solubility of nicotine extracted from tobacco leaves, found in the north of iran, in supercritical carbon dioxide has been measured. also the effects of pressure, temperature, extraction dynamic time, and the organic co-solvent on the amount of nicotine extracted from tobacco leaves have been investigated. it should be stressed that in order to reduce significantly the number ...

a viscosity model, based on eyring’s absolute rate theory combined with a cubic pr equation of state and wong-sandler mixing rule, has been proposed in order to correlate viscosities of aqueous solutions of alkanolamine mixtures at atmospheric pressure and different temperatures. in the proposed method, the energy and size parameters in studied equation of state (eos) have been obtained using t...

asphaltenes are the n-pentane or n-heptane insoluble fractions of crude oil that remain in solution under reservoir temperature and pressure conditions. they are destabilized and start to precipitate when the pressure, temperature and/or composition changes occur during primary production. the precipitated asphaltene particles will then grow in size and may start to deposit onto the production ...

a statistical mechanical based equation of state has been employed to calculate the liquid density of lead, mercury, bismuth and lead-bismuth and lead-lithium eutectic alloys.the equation is basically that of song, mason and ihm [ihm g, song y, mason ea. j. chem. phys.1991; 94: 3839] which is modified by ghatee and boushehri. three temperature dependent parameters are required to use this equat...

This paper presents the ability of a new group contribution equation of state in the prediction of thermodynamic properties of alcohols, ketones and ethers. This equation of state, called MCORGC, is based on the Chain-Of-Rotators Group Contribution equation considering a NRTL type local composition mixing rule. The group parameters required to predict the thermodynamic properties of the oxygena...

a new simple model is introduced for a liquid and an equation of state is derived based on this model and the statistical mechanical calculations. this equation of state works well for the non-polar and slightly polar liquids. the important conclusion that may be deduced from this equation of state is that if the reduced variables of state are chosen and defined appropriately, then, the princip...

This work develops a perturbation approach to the estimation and propagation of states in nonlinear dynamical systems with uncertainties in both the process model and output measurements. The state estimation error and statistical moments are propagated in time through a regular perturbation method in an artificial ordering parameter λ, while the state updating occurs through a linear update eq...