نتایج جستجو برای: amides
تعداد نتایج: 3739 فیلتر نتایج به سال:
Fe3O4 nanoparticles were employment as an efficient and magnetically separable Nano catalyst for the synthesis of amides via one-pot Beckmann rearrangement of ketones under solvent-free conditions. Various secondary amides were synthesized by this method in moderate to good yields. The catalyst showed high thermal stability and was recovered and reused at least five times without any considerab...
Amino-amides are important pharmaceutical building-blocks. The enantioselective reduction of trichloromethyl ketones using ruthenium transfer hydrogenation catalysts is reported. The products react in a range of Jocic-type reactions to give enantiomerically enriched amino-amides.
An efficient and general copper-catalyzed Goldberg reaction at 90-110 °C between aryl bromides and amides providing the desired products in good to excellent yields has been developed using N,N-dimethylglycine as the ligand. The reaction is tolerant toward a wide range of amides and a variety of functional group substituted aryl bromides. In addition, hindered, unreactive aromatic and aliphatic...
wall carbohydrates, and organic acids. The hydroxycinnamic acid amides with tyramine and octopamine are also common types of conjugates.2) The formation of the amides serves a defensive purpose in solanaceous plants such as potato,3・4) tobacco5) and tomato.6) Various forms of stress, including physical injury, infection with pathogens and elicitor-treatments, induce the accumulation of hydroxyc...
Bisamides are key fragments for the introduction of gem-diaminoalkyl residues into retroinverso pseudopeptide derivatives and in the synthesis of peptidomimetic compounds. The literature methods for these types of compounds have certain drawbacks. In particular, when amides react with electrophile-activated DMSO, the yields are rather low. We have found new electrophiles, 2,4,6-trichloro[1,3,5]...
the synthesis of aryl amides via the reactions of carboxylic acids and isocyanides in methanol was carried out in 78-95% yields under ultrasound irradiation. the method has wide applicability, and the protocol is mild, fast and efficient compared to the existing methods based on silent conditions.
Amides are a class of easily available and highly stable compounds. Secondary amides also serve as powerful directing groups in C H activation. Ketones are also a class of extremely versatile molecules that enable a number of fundamental transformations in organic synthesis. Hence the transformation of amides into ketones is of high relevance in organic synthesis. However, because of the high s...
The Cover Feature illustrates the photochemical conversion of carboxylic acids to Weinreb and morpholine amides. Sunlight or LED 370 nm irradiation mediates direct coupling N,O-dimethylhydroxylamine in presence 4-dimethylaminopyridine bromotrichloromethane, providing corresponding amides satisfactory high yields. More information can be found Research Article by C. G. Kokotos, Kokotos et al.
Ten novel hydrogen-bonding catalysts based on open-chain P(V)-amides of BINOL and chinchona alkaloids as well as three catalysts based on rigid cis-P(V)-cyclodiphosphazane amides of N (1),N (1)-dimethylcyclohexane-1,2-diamine have been developed. Employed in the asymmetric Michael addition of 2-hydroxynaphthoquinone to β-nitrostyrene, the open-chain 9-epi-aminochinchona-based phosphorus amides ...
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