نتایج جستجو برای: adsorption enthalpy

تعداد نتایج: 60415  

Journal: :The journal of physical chemistry. B 2012
Shih-Wei Hung Pai-Yi Hsiao Ming-Chang Lu Ching-Chang Chieng

Understanding protein adsorption onto solid surfaces is of critical importance in the field of bioengineering, especially for applications such as medical implants, diagnostic biosensors, drug delivery systems, and tissue engineering. This study proposed the use of molecular dynamics simulations with potential of mean force (PMF) calculations to identify and characterize the mechanisms of adsor...

Journal: :Nanotechnology 2009
J J Purewal H Kabbour J J Vajo C C Ahn B Fultz

Pore size distributions (PSD) and supercritical H2 isotherms have been measured for two activated carbon fiber (ACF) samples. The surface area and the PSD both depend on the degree of activation to which the ACF has been exposed. The low-surface-area ACF has a narrow PSD centered at 0.5 nm, while the high-surface-area ACF has a broad distribution of pore widths between 0.5 and 2 nm. The H2 adso...

2017
Xiuzhen Yang Yuezhou Zhang Liping Wang Lili Cao Kelin Li Andrew Hursthouse

The adsorption of 1-naphthol (NAP) in aqueous solution was investigated using unmodified and modified diatomite at different temperature, pH, adsorbent mass and contact time. The adsorption capacity of the modified diatomite significantly improved (about 2 times at 298 K) compared to the unmodified diatomite. The adsorption showed a good fit with the Langmuir model. The further data analysis de...

2014
G Sekaran M Mariappan

One of the wastewaters from tanning industry (soak liquor) contains 0.4 g/L of dissolved protein. During coagulation and flocculation 41% of protein was removed. A suggestion has been made to remove the residual protein by adsorption technique. The optimum conditions for adsorption of Bovine Serum Albumin (BSA) on rice bran based activated carbon (RBAC) were arrived. Maximum adsorption of BSA t...

2012
Augustine O. Ifelebuegu

The mechanism, isotherms and kinetics of removal of two endocrine disrupting chemicals, 17β-estradiol (E2) and 17αethinyloestradiol (EE2) by activated carbon adsorption were investigated in an agitated non-flow batch adsorption studies. Mathematical models were used to describe the adsorption phenomenon with the kinetic and thermodynamic parameters evaluated using the adsorption equilibrium dat...

2017
Shayan Shahbazi S Adam Stratz John D Auxier Daniel E Hanson Matthew L Marsh Howard L Hall

This work reports the thermodynamic characterizations of organometallic species as a vehicle for the rapid separation of volatile nuclear fission products via gas chromatography due to differences in adsorption enthalpy. Because adsorption and sublimation thermodynamics are linearly correlated, there is considerable motivation to determine sublimation enthalpies. A method of isothermal thermogr...

Narges Samadani Langeroodi Sepideh Mehrani Vida Jodaian

The adsorption of malonic acid on the rice bran was studied under various conditions such as temperature, contact time, adsorbent dose and concentration of adsorbate. Batch adsorption experiments were conducted and the result showed that the adsorption was dependent on all these parameters. The adsorption process obeys the Langmuir and Freundlich adsorption isotherms. The adsorption capacity wa...

1996
M. Domingo-Garcia F. J. López-Garzón C. Moreno-Castilla M. Pyda

The adsorption of several organic molecules on four carbon materials is studied by inverse gas solid chromatography at zero surface coverage. The specific retention volumes and the differential heats of adsorption (or standard enthalpies of adsorption) are used to study the influence of the porous structure and the chemical surface groups in the process. From the comparison of the differential ...

2017
Xiaotao Zhang Yinan Hao Ximing Wang Zhangjing Chen

A low-cost activated carbon (XSBLAC) prepared from XanthocerasSorbifoliaBungehull via chemical activation was investigated to determine its adsorption and desorption properties for zinc(II) ions from aqueous solutions. XSBLAC was characterized based on its N₂-adsorption/desorption isotherm, EDX, XRD, SEM and FTIR results. An adsorption study was conducted in a series of experiments to optimize ...

Journal: :Journal of hazardous materials 2007
Mehmet Emin Argun Sukru Dursun Celalettin Ozdemir Mustafa Karatas

This paper describes the adsorption of heavy metal ions from aqueous solutions by oak (Quercus coccifera) sawdust modified by means of HCl treatment. Our study tested the removal of three heavy metals: Cu, Ni, and Cr. The optimum shaking speed, adsorbent mass, contact time, and pH were determined, and adsorption isotherms were obtained using concentrations of the metal ions ranging from 0.1 to ...

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