Abstract. There is growing interest in developing spatially resolved methane (CH4) isotopic source signatures to aid geographic attribution of CH4 emissions. hydrogen isotope measurements (?2H–CH4) have the potential be a powerful tool for differentiation emissions from freshwater environments, as well other microbial sources. This because ?2H–CH4 values are partially dependent on ?2H environme...

Designing and searching for a high thermal conductivity material in both bulk nanoscale is highly demanding electronics cooling. In this work, we studied the of 2H-Germanium Carbide(2H-GeC) using first principles calculations. At 300 K, are reporting 1350 Wm?1K?1 1050 along a-axis c-axis respectively pure 2H-GeC. These values 130% higher than 2H-silicon carbide 20% lower cubic germanium carbide...

The 2H quadrupolar coupling is an excellent nuclear magnetic resonance (NMR) probe of segmental orientation, molecular dynamics, or hydrogen-bonding in solids and liquid crystals.1,2 It has provided information on protein dynamics3 and structure,4 on motions in polymers,5 on bond-order parameters in liquid crystals,6 on dynamics of guest molecules in zeolites,7 clays,8 and inclusion compounds,9...

Utilization of Photodisintegration reaction of Deuterium, 2H(?,n)1H, is a precise technique for determining the percentage of 2H in tritiated and natural water. The 23Na(n,?)24Na reaction is a suitable ?-source for producing the 2H(?,n)1H reaction. Tehran Research Reactor was used as a neutron source for producing 24Na isotopes. The BF3 detectors were used to detect the neutron emission of H2 c...

The photodenitrogenation of vinyl azides to 2H-azirines by using a photoflow reactor is reported and compared with thermal formation of 2H-azirines. Photochemically, the ring of the 2H-azirines was opened to yield the nitrile ylides, which underwent a [3 + 2]-cycloaddition with 1,3-dipolarophiles. When diisopropyl azodicarboxylate serves as the dipolarophile, 1,3,4-triazoles become directly acc...

A series of new 3,5-disubstituted-tetrahydro-2H-1,3,5-thiadiazine-2-thione (THTT) derivatives (4a-g) were prepared using a convenient and general one-pot procedure and evaluated for their in vitro antibacterial and antifungal activities by using the microdilution method in comparison with ampicillin and fluconazole. 3-Phenyl-5-(1-phenylethyl)-tetrahydro-2H-1,3,5-thiadiazine-2-thione (4a) and 3p...

Compound 1: H NMR (500 MHz, DMSO-d6) δ 11.64 (s, 1H), 8.73 (s, 4H), 8.57 (d, J = 1.4 Hz, 1H), 8.16 (dd, J = 8.9, 1.4 Hz, 1H), 7.81 (d, J = 8.5 Hz, 2H), 7.64 (d, J = 8.5 Hz, 2H), 6.99 (d, J = 8.9 Hz, 1H), 4.08 (t, J = 7.0 Hz, 2H), 3.28 (m, 2H), 1.69 (quin, J = 7.0 Hz, 2H), 1.33 (m, 8H), 0.86 (t, J = 6.8 Hz, 3H). C NMR (125 MHz, DMSO-d6) δ 162.6 (2xC = 0), 162.3 (2xC = 0), 158.9, 155.1, 151.9, 14...

UNLABELLED Synthesis of 2'-5'-oligoadenylates (2-5A) by oligoadenylate synthetase (OAS) is an important innate cellular response that limits viral replication by activating the latent cellular RNase, RNase L, to degrade single-stranded RNA. Some rotaviruses and coronaviruses antagonize the OAS/RNase L pathway through the activity of an encoded 2H phosphoesterase domain that cleaves 2-5A. These ...

The stem and leaves of Gasteria bicolor afforded three new dihydroanthracenones namely 3,4-dihydro-2,6,9-trihydroxy-8-methyl-1(2H)-anthracenone (gasteriacenone A), 3,4-dihydro-2,4,9-trihydroxy-6-methoxy-8-methyl-1(2H)-anthracenone (gasteriacenone B) and 3,4-dihydro-4,6,9-trihydroxy-7-carbomethoxy-8-methyl-1(2H)-anthraceno ne (gasteriacenone C). Their structures were determined by spectroscopic ...