The molecular characterization of bioactive food components is necessary for understanding the mechanisms of their beneficial or detrimental effects on human health. This study focused on γ-conglutin, a well-known lupin seed N-glycoprotein with health-promoting properties and controversial allergenic potential. Given the importance of N-glycosylation for the functional and structural characteri...

We present a simple example of toughening mechanism in the homogenization of composites with soft inclusions, produced by crack deflection at microscopic level. We show that the mechanism is connected to the irreversibility of the crack process. Because of that it cannot be detected through the standard homogenization tool of the Γ-convergence.

We prove the Γ-convergence of the one-dimensional Allen-Cahn action functional in the sharp-interface limit. In previous work, a good lower bound was developed under the assumption of single multiplicity, but the bound deteriorated in the case of higher multiplicity interfaces. We develop an improved bound by working directly with the limiting energy measures.

We characterize the macroscopic effective mechanical behavior of a graphene sheet modeled by a hexagonal lattice with twoand three-point atomic interactions, using Γ-convergence.

We prove that the family of functionals (Iδ) defined by Iδ(g) = ∫∫ RN×RN |g(x)−g(y)|>δ δ |x− y|N+p dx dy, ∀ g ∈ L(R ), for p ≥ 1 and δ > 0, Γ-converges in L(R ), as δ goes to 0, when p ≥ 1. Hereafter | | denotes the Euclidean norm of R . We also introduce a characterization for BV functions which has some advantages in comparison with the classic one based on the notion of essential variation o...

We study homogenization by Γ-convergence, with respect to the L1-strong convergence, of periodic multiple integrals in W 1,∞ when the integrand can take infinite values outside of a convex bounded open set of matrices.

We consider a sequence of linear Dirichlet problems as follows

Imidazolium bromide-based ionic liquids bearing phosphonyl groups on the cationic part were synthesized and grafted on γ-alumina (γ-Al₂O₃) powders. These powders were prepared as companion samples of conventional mesoporous γ-alumina membranes, in order to favor a possible transfer of the results to supported membrane materials, which could be used for CO₂ separation applications. Effective gra...

New polyanionic modifications of polyamide nucleic acid mimics were obtained. Thymine decamers were synthesized from respective chiral α- and γ-monomers, and their enantiomeric purity was assessed. Here, we present the decamer synthesis, purification and characterization by MALDI-TOF mass spectrometry and an investigation of the hybridization properties of the decamers. We show that the modifie...