We report the synthesis of alloyed quaternary and quinary nanocrystals based on copper chalcogenides, namely, copper zinc selenide-sulfide (CZSeS), copper tin selenide-sulfide (CTSeS), and copper zinc tin selenide-sulfide (CZTSeS) nanoplatelets (NPLs) (∼20 nm wide) with tunable chemical composition. Our synthesis scheme consisted of two facile steps: i.e., the preparation of copper selenide-sul...

Hydrogen sulfide is an essential gasotransmitter associated with numerous pathologies. We assert that hydrogen sulfide plays an important role in regulating macrophage function in response to subsequent inflammatory stimuli, promoting clearance of leukocyte infiltrate and reducing TNF-α levels in vivo following zymosan-challenge. We describe two distinct methods of measuring leukocyte hydrogen ...

This study was focused on how to improve the gas sensing properties of resistive gas sensors based on zinc oxide to dimethyl sulfide (DMS). The aim of this research was to investigate possible ways of improvement detection of dimethyl sulfide, such as volume doping with synthesized gold nanoparticles or applying sepiolite passive filter. The addition of noble metal into the gas sensing layer is...

Microwave technology has a potential application in the extraction of zinc from sulphide ores, knowledge of the dielectric properties of these ores plays a major role in the microwave design and simulation for any process. The dielectric properties of zinc sulfide concentrate for two different apparent densities—1.54 and 1.63 g/cm3—have been measured by using the resonance cavity perturbation t...

Nanoparticles may contain unusual forms of structural disorder that can substantially modify materials properties and thus cannot solely be considered as small pieces of bulk material. We have developed a method to quantify intermediate-range order in 3.4-nanometer-diameter zinc sulfide nanoparticles and show that structural coherence is lost over distances beyond 2 nanometers. The zinc-sulfur ...

In the absence of iron, dissolution of zinc sulfide was enhanced by the action of Acidithiobacillus caldus at 40 o C. The bioleaching mechanism was similar to that observed for mesophilic species of Acidithiobacillus at 30 o C, although the final metal recovery was lower. When iron was added to the cultures, the solubilization of zinc and copper from the sulfides was higher than that in sterile...

use of zinc and iron oxide are common in the desulfurization process from natural gas. in thisresearch, after determinations of the size and specifications through tem and xrd for each of the metaloxides, two different size ratios were used, 0.66 for zinc oxide and 0.142 for iron oxide. further, absorption of sulfur compounds in gas (hydrogen sulfide (h2s), carbonyl sulfide (cos), methyl mercap...