Catalytic performances of alloy and surface alloy are sensitive to the surface structures and composition. In this paper we present an overall survey of the surface structure of Pd(111) covered with different amount of Zn using Monte Carlo simulations. We demonstrate that the composition of PdZn surface alloy is Zn coverage dependent: the surface concentration of Zn increases with the increase ...

We present an empirical model for the electron energy relaxation time. It is based on Monte-Carlo simulation results, and is applicable to all relevant diamond and zinc-blende structure semiconductors. The energy relaxation times are expressed as a function of the carrier and lattice temperatures and, in the case of semiconductor alloys, the material composition. keywords: energy relaxation tim...

We present an empirical model for the electron energy relaxation time. It is based on Monte-Carlo simulation results and is applicable to all relevant diamond and zinc-blende structure semiconductors. The energy relaxation times are expressed as functions of the carrier and lattice temperatures, and in the case of semiconductor alloys, of the material composition. # 1999 Elsevier Science Ltd. A...

Ca(x)Zn(1-x)O alloys are potential candidates to achieve wide band-gap, which might significantly promote the band gap engineering and heterojunction design. We performed a crystal structure search for CaO-ZnO system under pressure, using an ab initio evolutionary algorithm implemented in the USPEX code. Four stable ordered Ca(x)Zn(1-x)O structures are found in the pressure range of 8.7-60 GPa....

Corrosion tests of 1015 low-carbon steel and two stainless steels (410 and 316L) were conducted in a pure zinc bath (99.98 wt pct Zn) in order to better understand the reaction mechanisms that occur during the degradation of submerged hardware at industrial general (batch) galvanizing operations. Through this testing, it was found that, in general, 316L stainless steel showed the best dissoluti...

a complexometric method for the determination of titanium in the presence of other metal ions based on the selective masking ability of 5-sulphosalicylic acid towards titanium is described. titanium (iv) present in a given sample solution is complexed with a known excess of edta and surplus edta is titrated against zinc sulphate solution at ph 5-6 using xylenol orange as the indicator. a known ...

Slow strain rate tests were performed on quenched and tempered AISI 4340 steel to measure the extent of hydrogen embrittlement caused by electroplating with zinc-cobalt alloys. The effects of bath composition and pH were studied and compared with results for electrodeposited cadmium and zinc-10%nickel. It was found that Zinc-1%cobalt alloy coatings caused serious hydrogen embrittlement (EI 0.63...

Zinc-Nickel electrodeposits have been widely adopted for surface treatment of automobile steel sheet for high corrosion resistance. In this work the effect of pulse parameters on the Zn-Ni alloy electrodeposits was investigated. The hardness, thickness, corrosion resistance and composition of deposits thus produced were investigated. The surface topography of the deposits was also observed in S...

Twenty-six objects (1st to the 3rd century AD) found at the archaeological site of Thamusida (Morocco), which is a military settlement between the 1st and the 3rd century AD, have been investigated by means of portable X-ray fluorescence and time of flight-neutron diffraction. The combination of element-sensitive X-ray fluorescence and structure-sensitive neutron diffraction yields, in a totall...

The utilization of the quantum properties of the electron spin wave function will allow the development of a new class of devices. The problem is still controversial and unsettled, even qualitatively, especially for concentrated spin systems such as 3d metals and their alloys. The variety of crystal structures of 3d metals makes difficult the direct comparison between the experimental results a...