A series of microstructured, supported platinum (Pt) catalyst films (supported on single-crystal yttria-stabilized zirconia) and an appropriate Pt catalyst reference system (supported on single-crystal alumina) were fabricated using pulsed laser deposition and ion-beam etching. The thin films exhibit area-specific lengths of the three-phase boundary (length of three-phase boundary between the P...

In recent years, 3 mol% yttria-stabilized tetragonal zirconia polycrystals (3Y-TZP) doped with copper oxide has obtained increasing interest due to its enhanced superplastisity and good potential in tribological applications. In this work, the effect of addition of small amounts (0.8 mol%) of copper oxide on the sintering behavior of 3Y-TZP was studied using a dilatometer and high-temperature X...

PURPOSE The purpose of this study was to compare the linear sintering behavior of presintered zirconia blocks of various densities. The mechanical properties of the resulting sintered zirconia blocks were then analyzed. MATERIALS AND METHODS Three experimental groups of dental zirconia blocks, with a different presintering density each, were designed in the present study. Kavo Everest® ZS bla...

BACKGROUND Zirconia was introduced as an alternative to alumina for use in the femoral head. The yttria stabilized zirconia material was improved by adding alumina. We evaluated highly cross-linked polyethylene wear performance of zirconia in total hip arthroplasty. The hypothesis was that alumina stabilized zirconia could decrease highly cross-linked polyethylene wear. METHODS Highly cross-l...

The microstructure and morphology of solid-oxide fuel-cell electrodes are very complex but important because they strongly affect the electrical performance of the cell. In this work the high-resolution X-ray nanotomography technique is applied to reconstruct the three-dimensional microstructure of a (La(0.8)Sr(0.2))(0.95)MnO(3) yttria-stabilized zirconia composite cathode. Some key microstruct...

The optical transmission and indices of refraction for the cubic isomorph of ZrO(2) stabilized with 12.0-mol % Y(2)O(3) were measured at various temperatures and for a range of wavelengths from 0.36 to 5.1 microm. Index data to +/-5 x 10(-5) were fitted to a three-term Sellmeier equation. The value of N(D) = 2.15847. The dispersion N(G) - N(B) = 0.06044, while that for N(c) - N(f) = 0.03455. Th...

Yttria stabilized zlrconia doped with Bi203 shows an efficient luminescence due to the Bi 3+ ions. Two luminescent centres were observed which are ascribed to BIO 8 and BiO 7 groups.

A nonaqueous synthetic route for the preparation of a regular crystalline yttria mesostructure is presented. The reaction between yttrium alkoxides and benzyl alcohol results in the formation of a highly ordered lamellar nanocomposite consisting of yttria layers with a confined thickness of about 0.6 nm, separated from each other by organic layers of intercalated benzoate molecules. Doping with...