In this study we have investigated the possibility of processing waste rubber gloves using pyrolysis. Y-zeolite catalyst was employed to upgrade the pyrolysis products to give higher yields of valuable aromatic compounds such as toluene and xylenes. The composition of the pyrolysis products was determined using gas chromatography with linked mass spectrometry (GC-MS), gas chromatograph equipped...

A novel synthetic route is designed, employing both high temperature and a nontoxic organic structure-directing agent (SDA), for the synthesis of high silica zeolite Y. The N-methylpyridinium used as an organic SDA is stable during the synthesis, and the high silica zeolite Y shows high hydrothermal stability and good catalytic performance, as well as excellent adsorptive properties.

Synthesis of nanoparticles of TiO2, Pt, CdS, and their binary and ternary combinations were made on zeolite Y starting frommolecular precursors that are ion exchanged into the zeolite.Nanoclusters ofTiO2 in the anatase formwere formed from titanyl ions at low loadings of Ti (1 per 2.5 supercages). CdS (hexagonal form) andmetallic Pt were formed fromCd2þ and Pt(NH3)4 2þ ion exchanged into the ze...

A novel utilization method of filter residue from the preparation process of zeolite-based catalysts was investigated. Y zeolite and a fluid catalytic cracking (FCC) catalyst were synthesized from filter residue. Compared to the Y zeolite synthesized by the conventional method, the Y zeolite synthesized from filter residue exhibited better thermal stability. The catalyst possessed wide-pore dis...

Zeolites A and X were co-crystallized in controlled ratios from one synthesis gel. With increasing potassium content of the synthesis gel or increasing proportion of Na-Y seeds in a mixture of Na-Y and Na-A seeds, the ratio of zeolite X to zeolite A in the synthesis product increased.

Structured catalysts formed from the growth of zeolites on substrates is an area of increasing interest due to the increased efficiency of the catalytic process, and the ability to provide superior heat transfer and thermal conductivity for both exothermic and endothermic processes. However, the generation of structured catalysts represents a significant challenge when balancing the relationshi...

In this study, adsorption measurement of various chlorinated hydrocarbons on Y-type zeolites were performed using the chromatographic method to examine the adsorption phenomena. Dichloromethane (DCM), chloroform (TCM), trichloroethylene (TCE), and tetrachloroethylene (PCE), were used as the chlorinated hydrocarbons, and PQ-USY, USY-6.18, Na-Y, HSZ-390HUD, Pentasile-2 and Pentacil-1 were used as...

this work undertakes the study of the detoxification reactions of o, s-dimethyl phosphoramidithioate (methamidophos) as an organophophorus insecticide on the 14.7 wt% magnetite (fe3o4) nanoparticles/ag-nay faujasite molecular sieve zeolite (fmsz) composite. the influence of solvent (methanol, acetonitrile and n-hexane) on the detoxification potential of composite was investigated. for this surv...

We show that a Gaussian-shaped pulse can be used to excite selected 1H signals in hydroxyapatite, monetite and H-Y zeolite loaded with trimethylphosphine oxide (TMPO). This selective excitation method can be incorporated into Lee-Goldburg (LG) cross-polarization to obtain useful spectral editing opportunity. This new strategy has been applied to identify the Brønsted and the Lewis acid sites in...

Stabilization techniques for low-valent organometallic species in acidic forms of large-pore zeolite Y are reported. The intrazeolite surface chemistry and thermal stability of MesSnCo(CO)4 in HY zeolites (I&NaloA155Si1370384 and H16Na39A155Sil370384) were studied with X-ray absorption spectroscopy (Sn, Co edge EXAFS) and in-sifu FTIR/TPD-MS techniques. The acidic zeolite Y host offers a chemic...