Background: Polysaccharides are renewable biodegradable natural materials and are accounted for to control the formation of hybrid silica nanocomposites by sol gel process. Methods: The synthesis of templated silica xerogel essentially includes two critical steps of hydrolysis and polycondensation reaction that are started by catalyst and silica precursor solution. Aside from this Saponificatio...

V2O5 xerogel films were fabricated by casting V2O5 sols onto fluorine-doped tin oxide glass substrates at room temperature. Five, ten and twenty atomic layers of Al2O3 were grown onto as-fabricated films respectively. The bare film and Al2O3-deposited films all exhibited hydrous V2O5 phase only. Electrochemical impedance spectroscopy study revealed increased surface charge-transfer resistance o...

Many polymers and composites have been used to prepare active wound dressings. These materials have typically exhibited potentially toxic burst release of the drugs within the first few hours followed by a much slower, potentially ineffective drug release rate thereafter. Many of these materials also degraded to produce inflammatory and cytotoxic products. To overcome these limitations, composi...

An amperometric sol-gel derived sensor that both releases nitric oxide (NO) and measures physiologically relevant concentrations of oxygen (PO2) is described. The sensor consists of a platinum electrode coated with an aminosilane/ethyltrimethoxysilane hybrid xerogel film. Hydrophilic polyurethane (HPU) is doped into the hybrid film to reduce sensor hydration time and increase oxygen permeabilit...

various concentrations of copper were embedded into silica matrix to xerogel forms using copper source cu(no3)2∙3h2o. the xerogel samples were prepared by hydrolysis and condensation of tetraethyl ortho-silicate (teos) with determination of new molar ratio of the components by the sol-gel method. after ambient drying, the xerogel samples were heated from 60 to 1000˚c at a slow heating rate (50°...

A complex of salmon milt deoxyribonucleic acid (DNA) and the cationic surfactant cetyltrimethylammonium (CTMA) forms an organic-soluble biomaterial that can be readily incorporated within an organically modified silane-based xerogel. The photoluminescence (PL) intensity and excited-state luminescence lifetime of tris(4,7'-diphenyl-1,10'-phenanathroline) ruthenium(II) [(Ru(dpp)3](2+), a common O...

Carbon xerogel-zinc oxide (CXZnO) composites were synthesized by a simple method of sol-gel condensation polymerization of formaldehyde and resorcinol solution containing zinc salt followed by drying and thermal treatment. ZnO nanoparticles were observed to be evenly dispersed on the surfaces of the carbon xerogel microspheres. The as-prepared CXZnO composites were mixed with laccase (Lac) and ...

Gas-tight dense membranes of highly Sr-doped LaCoO, (such as the composition La,,, Sr 0,7 COO, chosen in this study) are difficult to prepare using usual synthesis processes. This report presents an aqueous sol-gel route using metal acetates as precursors to achieve this goal. Hydrogen peroxide and ammonia are added to the acetates precursor solution to obtain stable sol and xerogel, as well as...

The synthesis of a tertiary thiol-bearing silane precursor (i.e., N-acetyl penicillamine propyltrimethoxysilane or NAPTMS) to enable enhanced NO storage stability at physiological temperature is described. The novel silane was co-condensed with alkoxy- or alkylalkoxysilanes under varied synthetic parameters (e.g., water to silane ratio, catalyst and solvent concentrations, and reaction time) to...

various concentrations of copper are embedded into silica matrix to xerogel form using copper source - cu(no3)2∙3h2o. the xerogel samples are prepared by hydrolysis and condensation of tetraethyl orthosilicate (teos) by the sol-gel method  and with determination of new molar ratio of components h2o/teos to be 6.2. in this investigation, the necessary amount of trihydrated copper nitrate is adde...